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蒸汽密度
2.1 (vs air)
质量水平
蒸汽压
2.7 mmHg
等级
absolute
puriss.
方案
≥98.5% (GC)
表单
liquid
自燃温度
784 °F
质量
over molecular sieve
expl. lim.
7.3 %, 33 °F
杂质
≤0.01% water
water
折射率
n20/D 1.382 (lit.)
n20/D 1.382
pH值(酸碱度)
6.4 (20 °C, 0.01 g/L)
沸点
101.2 °C (lit.)
mp
−29 °C (lit.)
密度
1.127 g/mL at 25 °C (lit.)
SMILES字符串
C[N+]([O-])=O
InChI
1S/CH3NO2/c1-2(3)4/h1H3
InChI key
LYGJENNIWJXYER-UHFFFAOYSA-N
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一般描述
硝基甲烷是一种脂肪族硝基化合物。在金鸡纳生物碱衍生的手性双功能硫脲有机催化剂存在下,它与查耳酮发生 Michael 加成反应。研究了在 Co-ZSM5(沸石 Socony Mobil-5)存在下,其向 N 2 的转化。
应用
硝基甲烷可用于制备钴笼络合物。
警示用语:
Warning
危险分类
Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Carc. 2 - Flam. Liq. 3 - Repr. 2
储存分类代码
4.1A - Other explosive hazardous materials
WGK
WGK 2
闪点(°F)
95.0 °F - closed cup
闪点(°C)
35 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
易制爆化学品
危险化学品
The catalytic chemistry of nitromethane over Co-ZSM5 and other catalysts in connection with the methane-NOxSCR reaction.
Cowan AD, et al.
J. Catal., 176(2), 329-343 (1998)
Loay Awad
Experimental and therapeutic medicine, 19(3), 1835-1843 (2020-02-28)
Chemotherapy and radiation are unable to eliminate all cancer cells, particularly apoptosis-resistant cancer cells, despite their ability to kill cancer cluster cells. Thus, it is important to identify methods that eliminate all cancer cells in order to prevent relapse. Salinomycin
Xin Yang et al.
Environmental science & technology, 46(23), 12832-12838 (2012-11-17)
Nitrogenous disinfection byproducts (N-DBPs) such as haloacetonitriles (HANs) and halonitromethanes (HNMs) are formed during water chlorination. Preozonation is sometimes applied to control trihalomethane (THM) formation, but this may risk promoting the formation of HNMs and HANs. The role of ozone
F Ferreira da Silva et al.
The Journal of chemical physics, 135(17), 174504-174504 (2011-11-11)
Results of a detailed study on electron interactions with nitromethane (CH(3)NO(2)) embedded in helium nanodroplets are reported. Anionic and cationic products formed are analysed by mass spectrometry. When the doped helium droplets are irradiated with low-energy electrons of about 2
Construction of an all-carbon quaternary stereocenter by the peptide-catalyzed asymmetric Michael addition of nitromethane to β-disubstituted α,β-unsaturated aldehydes.
Kengo Akagawa et al.
Angewandte Chemie (International ed. in English), 51(51), 12786-12789 (2012-11-13)
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