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蒸汽密度
2.1 (vs air)
质量水平
蒸汽压
2.7 mmHg
等级
absolute
puriss.
检测方案
≥98.5% (GC)
形式
liquid
自燃温度
784 °F
质量
over molecular sieve
expl. lim.
7.3 %, 33 °F
杂质
≤0.01% water
water
折射率
n20/D 1.382 (lit.)
n20/D 1.382
pH值(酸碱度)
6.4 (20 °C, 0.01 g/L)
bp
101.2 °C (lit.)
mp
−29 °C (lit.)
密度
1.127 g/mL at 25 °C (lit.)
SMILES字符串
C[N+]([O-])=O
InChI
1S/CH3NO2/c1-2(3)4/h1H3
InChI key
LYGJENNIWJXYER-UHFFFAOYSA-N
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一般描述
硝基甲烷是一种脂肪族硝基化合物。在金鸡纳生物碱衍生的手性双功能硫脲有机催化剂存在下,它与查耳酮发生 Michael 加成反应。研究了在 Co-ZSM5(沸石 Socony Mobil-5)存在下,其向 N 2 的转化。
应用
硝基甲烷可用于制备钴笼络合物。
警示用语:
Warning
危险分类
Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Carc. 2 - Flam. Liq. 3 - Repr. 2
WGK
WGK 2
闪点(°F)
closed cup
闪点(°C)
closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
易制爆化学品
The catalytic chemistry of nitromethane over Co-ZSM5 and other catalysts in connection with the methane-NOxSCR reaction.
J. Catal., 176(2), 329-343 (1998)
Metal ion encapsulation: cobalt cages derived from polyamines, formaldehyde, and nitromethane.
Journal of the American Chemical Society, 106(19), 5478-5488 (1984)
Experimental and therapeutic medicine, 19(3), 1835-1843 (2020-02-28)
Chemotherapy and radiation are unable to eliminate all cancer cells, particularly apoptosis-resistant cancer cells, despite their ability to kill cancer cluster cells. Thus, it is important to identify methods that eliminate all cancer cells in order to prevent relapse. Salinomycin
Chemistry, an Asian journal, 7(4), 771-777 (2012-02-10)
Through the cleavage of the C-C bond, the first catalytic tandem conjugate addition-elimination reaction of Morita-Baylis-Hillman C adducts has been presented. Various S(N)2'-like C-, S-, and P-allylic compounds could be obtained with exclusive E configuration in good to excellent yields.
Concise Encyclopedia Chemistry, 696-696 (1994)
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