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Merck
CN

73148

Supelco

3-硝基苯甲醇

suitable for mass spectrometry (MS), ≥99.5%

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别名:
NOBA
线性分子式:
O2NC6H4CH2OH
CAS号:
分子量:
153.14
Beilstein:
2044769
EC 号:
MDL编号:
UNSPSC代码:
12000000
PubChem化学物质编号:
NACRES:
NA.21

质量水平

检测方案

≥99.5% (GC)
≥99.5%

形式

(Powder or Crystals or Solid or Liquid)

技术

H-NMR: suitable
mass spectrometry (MS): suitable

bp

175-180 °C/3 mmHg (lit.)

mp

26-32 °C (lit.)

密度

1.29 g/mL at 20 °C (lit.)

SMILES字符串

OCc1cccc(c1)[N+]([O-])=O

InChI

1S/C7H7NO3/c9-5-6-2-1-3-7(4-6)8(10)11/h1-4,9H,5H2

InChI key

CWNPOQFCIIFQDM-UHFFFAOYSA-N

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一般描述

3-硝基苯甲醇(3-NBA)是最常用的色谱基质。可用于分析卟啉、环肽、碰撞活化用碱金属阳离子化脂肪酸以及某些有机钌化合物。

应用

3-硝基苯甲醇在液体二次离子质谱法中已用作电离时的液体基质。

其他说明

用作快原子轰击质谱技术的基质。

WGK

WGK 3

闪点(°F)

233.6 °F

闪点(°C)

112 °C

个人防护装备

Eyeshields, Gloves


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T.W. Chan et al.
Org. Mass Spectrom., 27, 53-53 (1992)
J. Meili et al.
Org. Mass Spectrom., 19, 581-581 (1984)
3-Nitrobenzyl alcohol has wide applicability as a matrix for FAB-MS.
Sweetman, Brian J., and Ian A. Blair.
Biological Mass Spectrometry, 17.4, 337-340 (1988)
Harry J Sterling et al.
Journal of the American Society for Mass Spectrometry, 20(10), 1933-1943 (2009-08-18)
The use of m-nitrobenzyl alcohol (m-NBA) to enhance charging of noncovalent complexes formed by electrospray ionization from aqueous solutions was investigated. Addition of up to 1% m-NBA can result in a significant increase in the average charging of complexes, ranging
Yuya Domoto et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 20(48), 15998-16005 (2014-10-07)
Efficient end-capping synthesis of neutral donor-acceptor (D-A) [2]rotaxanes without loading any catalysts or activating agents was achieved by utilizing high reactivity of a pentacoordinated hydrosilane toward salicylic acid derivatives. As components of [2]rotaxanes, an electron-deficient naphthalenediimide-containing axle with a salicylic

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