72240
铝镍合金
50% Al basis, 50% Ni basis, powder, purum,
别名:
Raney® 镍合金, 镍铝合金
产品名称
铝镍合金, purum, 50% Al basis, 50% Ni basis
SMILES string
[Al].[Ni]
InChI
1S/Al.Ni
InChI key
NPXOKRUENSOPAO-UHFFFAOYSA-N
grade
purum
form
powder
composition
Al, 50%
Ni, 50%
reaction suitability
core: nickel
reagent type: catalyst
Quality Level
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Application
铝镍合金可用于：
- 将腈类、硝基和肟类化合物还原为一级胺。
- 将羰基化合物转化为烃类物质。
- 作为还原剂将Ar-X衍生物转化为Ar-H化合物。
- 合成雷尼镍催化剂，用作烷化剂。
- 通过碱浸法合成非自燃镍催化剂。
- 合成合金的骨架镍催化剂。
Legal Information
Raney is a registered trademark of W.R. Grace & Co.-Conn.
signalword
Danger
hcodes
Hazard Classifications
Carc. 2 - Flam. Sol. 1 - Skin Sens. 1 - Water-react 2
存储类别
4.3 - Hazardous materials which set free flammable gases upon contact with water
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
法规信息
危险化学品
此项目有
Reduction of carbonyl groups to the corresponding methylenes with Ni-Al alloy in water.
Ishimoto K, et al.
Chemical Communications (Cambridge, England), 89(4), 514-515 (2003)
Reinvestigating Raney nickel mediated selective alkylation of amines with alcohols via hydrogen autotransfer methodology.
Mehta A, et al.
Applied Catalysis A: General, 478(4), 241-251 (2014)
An environmentally benign and catalytically efficient non-pyrophoric Ni catalyst for aqueous-phase reforming of ethylene glycol.
Zhu LJ, et al.
Green Chemistry, 10(12), 1323-1330 (2008)
Highly selective hydrogenation of C?C double bond in unsaturated carbonyl compounds over NiC catalyst.
Mahata N, et al.
Chemical Engineering Journal, 188(4), 155-159 (2012)
Nickel-aluminum alloy as a reducing agent.
Keefer LK and Lunn G
Chemical Reviews, 89(3), 459-502 (1989)
商品
Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.
An article concerning self-propagating reactions induced by mechanical alloying, presented by Sigma-Aldrich.com.
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