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一般描述
乙醇钠是一种烷氧基盐,主要作为强碱用于脱质子化、脱水和脱卤等有机反应。
乙醇钠(乙酸钠)是一种醇钠。它是由钠与乙醇反应合成的。在水存在下发生分解,生成乙醇和氢氧化钠。它被广泛用作有机合成研究的强碱。
应用
三羰基氯(甘氨酸)钌 (II) (CORM-3) 的制备可使用乙醇钠。
乙醇钠可用作钯催化的芳基卤化物和烯基硼烷交叉偶联反应的碱,以合成芳基化 ( E )-烯烃。
警示用语:
Danger
危险声明
危险分类
Flam. Sol. 1 - Self-heat. 1 - Skin Corr. 1A
补充剂危害
储存分类代码
4.2 - Pyrophoric and self-heating hazardous materials
WGK
WGK 1
闪点(°F)
86.0 °F - closed cup
闪点(°C)
30 °C - closed cup
法规信息
监管及禁止进口产品
Whitaker KS and Whitaker DT
e-EROS Encyclopedia of Reagents for Organic Synthesis (2001)
Stereoselective synthesis of arylated (E)-alkenes by the reaction of alk-1-enylboranes with aryl halides in the presence of palladium catalyst.
Miyaura N & Suzuki, A.
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James E Clark et al.
Circulation research, 93(2), e2-e8 (2003-07-05)
Carbon monoxide, which is generated in mammals during the degradation of heme by the enzyme heme oxygenase, is an important signaling mediator. Transition metal carbonyls have been recently shown to function as carbon monoxide-releasing molecules (CO-RMs) and to elicit distinct
Eagleson M.
Concise Encyclopedia Chemistry, 997-997 (1994)
Ali Reza Harifi-Mood et al.
Journal of pharmacy & pharmaceutical sciences : a publication of the Canadian Society for Pharmaceutical Sciences, Societe canadienne des sciences pharmaceutiques, 7(1), 88-91 (2004-05-18)
Variable-Temperature Kinetics has been used to obtain the rate constants of the reaction at various temperatures during one kinetic run. Pseudo-first-order rate constants for the transesterification of procaine with aliphatic alcohols ethanol, n-propanol and tert-butanol were obtained by the fluorescence
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