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Merck
CN

69875

Sigma-Aldrich

六羰基钼

technical

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别名:
羰化钼
线性分子式:
Mo(CO)6
CAS号:
分子量:
264.00
EC 号:
MDL编号:
UNSPSC代码:
12352300
PubChem化学物质编号:
NACRES:
NA.23

蒸汽密度

9.1 (vs air)

质量水平

等级

technical

形式

solid

反应适用性

core: molybdenum
reagent type: catalyst

bp

156 °C (lit.)

mp

150 °C (dec.) (lit.)

密度

1.96 g/mL at 25 °C (lit.)

SMILES字符串

[Mo].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]

InChI

1S/6CO.Mo/c6*1-2;

InChI key

KMKBZNSIJQWHJA-UHFFFAOYSA-N

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一般描述

Molybdenum hexacarbonyl is a colorless compound that sublimates and decomposes without melting at 150oC. It has an octahedral structure. Inherent sublimation of molybdenum hexacarbonyl permits it to perform as an active liquefaction catalyst. To form a catalyst it is adsorbed on dehydroxylated alumina forming subcarboyls.

应用

Alumina supported molybdenum hexacarbonyl acts as an active catalyst. It is used to synthesize MoO and MoC nanowires by electron beam induced deposition.

象形图

Skull and crossbones

警示用语:

Danger

危险声明

危险分类

Acute Tox. 3 Inhalation

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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Microstructural analysis and Transport Properties of MoO and MoC nanostructures prepared by focused electron beam-induced deposition
Makise K, et al
Scientific Reports, 4 (2014)
An investigation of the chemistry of molybdenum hexacarbonyl on thin dehydroxylated alumina films in ultrahigh vacuum
Catalysis Letters, 91(1-2), 83-88 (2003)
Qingxi Meng et al.
Journal of molecular modeling, 18(8), 3489-3499 (2012-02-03)
Density functional theory (DFT) was used to investigate the Mo-catalyzed intramolecular Pauson-Khand reaction of 3-allyloxy-1-propynylphosphonates. All intermediates and transition states were optimized completely at the B3LYP/6-31 G(d,p) level [LANL2DZ(f) for Mo]. In the Mo-catalyzed intramolecular Pauson-Khand reaction, the C–C oxidative
Paul Nissenson et al.
Physical chemistry chemical physics : PCCP, 8(40), 4700-4710 (2006-10-19)
While there is increasing evidence for unique chemical reactions at interfaces, there are fewer data on photochemistry at liquid-vapor junctions. This paper reports a comparison of the photolysis of molybdenum hexacarbonyl, Mo(CO)(6), in 1-decene either as liquid droplets or in
John Spencer
Future medicinal chemistry, 2(2), 161-168 (2011-03-24)
Microwave-mediated chemistry, involving the reduction of nitroarenes with molybdenum hexacarbonyl as a stoichiometric reducing agent, has been employed in the synthesis of a range of anilines. Many of these reactions exhibit high levels of chemoselectivity, tolerating unsaturation, steric hindrance and

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