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蒸汽密度
1.3 (vs air)
质量水平
蒸汽压
310 mmHg ( 55 °C)
71 mmHg ( 20 °C)
等级
purum
方案
≥95.0% (GC)
表单
liquid
包含
~0.5% acetic acid as stabilizer
~0.5% hydroquinone as stabilizer
expl. lim.
15.64 %
杂质
~5% water
折射率
n20/D 1.411 (lit.)
n20/D 1.412
沸点
81 °C (lit.)
密度
0.86 g/mL at 20 °C
0.864 g/mL at 25 °C (lit.)
储存温度
2-8°C
SMILES字符串
CC(=O)C=C
InChI
1S/C4H6O/c1-3-4(2)5/h3H,1H2,2H3
InChI key
FUSUHKVFWTUUBE-UHFFFAOYSA-N
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注意
储存时可变为褐色
警示用语:
Danger
危险分类
Acute Tox. 1 Dermal - Acute Tox. 1 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - Skin Sens. 1
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
19.4 °F - closed cup
闪点(°C)
-7 °C - closed cup
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
监管及禁止进口产品
Journal of the American Chemical Society, 130(20), 6322-6323 (2008-04-25)
Non-interpenetrating star polymer catalysts designed to mimic the site isolation characteristics of enzymes enable the one-pot combination of multiple otherwise incompatible catalysts for asymmetric cascade reactions that involve iminium, enamine, and H-bonding catalysis. Control experiments replacing star polymer catalysts with
Toxicology and applied pharmacology, 241(1), 1-13 (2009-08-18)
Diabetic nephropathy is characterized by increased oxidative stress and mitochondrial dysfunction. In the present study, we prepared primary cultures of proximal tubular (PT) cells from diabetic rats 30 days after an ip injection of streptozotocin and compared their susceptibility to
Molecules (Basel, Switzerland), 17(6), 7523-7532 (2012-06-20)
The enantioselective conjugate addition reaction of 3-aryl-substituted oxindoles with methyl vinyl ketone promoted by binaphthyl-modified bifunctional organocatalysts was investigated. The corresponding Michael adducts, containing a quaternary center at the C3-position of the oxindoles, were generally obtained in high yields with
The Journal of organic chemistry, 74(16), 6260-6265 (2009-07-23)
1,4-Addition of anilines onto Michael acceptors proceeds easily in specific polar protic solvents, without any promoting agent. According to the solvent and to the electrophile, the selectivity of the reaction can be finely tuned. With methyl acrylate as electrophile, only
The Journal of organic chemistry, 72(9), 3458-3466 (2007-03-31)
Diene substituent effects on the regiochemical and stereochemical outcomes of uncatalyzed Diels-Alder reactions of N-alkoxycarbonyl-1,2-dihydropyridines with both styrene and methyl vinyl ketone (MVK) were studied. Alkyl substitution on the diene in all cases examined resulted in a kinetic preference for
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