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Merck
CN

679186

乙腈 溶液

suitable for HPLC, contains 5 % (v/v) water, 0.1 % (v/v) formic acid, 0.05 % (w/v) ammonium formate

别名:

ACN, Cyanomethane, Ethyl nitrile, Methyl cyanide

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关于此项目

线性分子式:
CH3CN
化学文摘社编号:
分子量:
41.05
UNSPSC Code:
12190000
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
4124158
Grade:
HPLC grade
Technique(s):
HPLC: suitable
Bp:
81-82 °C (lit.)
Vapor pressure:
72.8 mmHg
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产品名称

乙腈 溶液, contains 0.05 % (w/v) ammonium formate, 5 % (v/v) water, 0.1 % (v/v) formic acid, suitable for HPLC

SMILES string

CC#N

InChI key

WEVYAHXRMPXWCK-UHFFFAOYSA-N

InChI

1S/C2H3N/c1-2-3/h1H3

grade

HPLC grade

vapor density

1.41 (vs air)

vapor pressure

72.8 mmHg

form

liquid

contains

0.05 % (w/v) ammonium formate
0.1 % (v/v) formic acid
5 % (v/v) water

expl. lim.

8 % (lit.)

technique(s)

HPLC: suitable

bp

81-82 °C (lit.)

mp

-48 °C (lit.)

density

0.782 g/mL at 25 °C
0.807 g/mL at 25 °C

format

mixture

Quality Level

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General description

通过 LC/MS 适用性测试

Preparation Note

产品经过 0.2μm 过滤器过滤

Application


  • Detection of Amino Acids via Chemiluminescence: Acetonitrile is employed in the detection of α-amino acids using peroxyoxalate chemiluminescence. A study demonstrated the use of a mixed solution of water, acetonitrile, and ethyl acetate for detecting amino acids, highlighting its efficacy in analytical applications. This method enhances the sensitivity and accuracy of amino acid detection, making it crucial for biochemical and clinical analyses (Kan et al., American Journal of Analytical Chemistry, 2020).

  • Redox Properties of N-Hydroxyimides: Acetonitrile mixed with sulfuric acid is used to study the redox properties of N-hydroxyimides, acting as a hydrogen atom transfer (HAT) mediator for alcohol oxidation. This application is significant in understanding the electrochemical behavior of organic compounds and developing new catalytic processes for oxidation reactions (Kishioka, Journal of Electroanalytical Chemistry, 2023).

  • Electrode Reactions in Catalytic Mediation: Acetonitrile solution is used in investigating the electrode reactions of N-hydroxyphthalimide in sulfuric acid. This study focuses on its role as a catalytic mediator for alcohol oxidation, providing insights into the electrochemical mechanisms involved. The findings contribute to the development of efficient catalytic systems for organic transformations (Kishioka, Journal of Electroanalytical Chemistry, 2022).

  • Excitation of Europium Complexes: Acetonitrile solution is utilized in the interaction of Eu(FOD)3 with xenon difluoride to study ligand-assisted excitation of Eu(III). This research explores the photophysical properties of europium complexes, which are essential for developing luminescent materials for various applications, including lighting and display technologies (Masyagutova et al., Journal of Fluorine Chemistry, 2024).


Other Notes

Discover LiChropur reagents ideal for HPLC or LC-MS analysis

Packaging

M-Bottle for Solvents
As a global leader in lab reagents, we are constantly looking for new ways to optimize the safety of our products. The newly developed 4L solvent bottle design features advanced sealing technology that eliminates leaks to make the handling of solvents safer and more convenient than ever before.
See all the new features here!

pictograms

FlameExclamation mark

signalword

Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 2

存储类别

3 - Flammable liquids

wgk

WGK 2

flash_point_f

36.0 °F - closed cup

flash_point_c

2.22 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

危险化学品
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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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In this study, the changes in UV absorbance at 254 nm (UVA254) and electron donating capacity (EDC) were investigated as surrogate indicators for assessing removal of micropollutants and bromate formation during ozonation of wastewater effluents. To measure the EDC, a novel
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Brain : a journal of neurology, 137(Pt 9), 2493-2508 (2014-07-27)
The neuropathological substrate of dementia in patients with Parkinson's disease is still under debate, particularly in patients with insufficient alternate neuropathology for other degenerative dementias. In patients with pure Lewy body Parkinson's disease, previous post-mortem studies have shown that dopaminergic
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Journal of proteome research, 13(9), 3905-3918 (2014-07-30)
SUMOylation is an essential posttranslational modification and regulates many cellular processes. Dysregulation of SUMOylation plays a critical role in metastasis, yet how its perturbation affects this lethal process of cancer is not well understood. We found that SUMO-2/3 modification is

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