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蒸汽密度
4.89 (vs air)
质量水平
蒸汽压
24.09 psi ( 55 °C)
7.89 psi ( 20 °C)
等级
purum
方案
≥99.0% (GC)
包含
silver wool as stabilizer
杂质
≤0.5% CH2I2
折射率
n20/D 1.530
n20/D 1.531 (lit.)
沸点
41-43 °C (lit.)
41-43 °C
mp
−64 (lit.)
溶解性
water: soluble 14 g/L at 20 °C
密度
2.28 g/mL at 25 °C (lit.)
官能团
alkyl halide
iodo
SMILES字符串
CI
InChI
1S/CH3I/c1-2/h1H3
InChI key
INQOMBQAUSQDDS-UHFFFAOYSA-N
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一般描述
碘甲烷(甲烷碘)是一种无色液体。它可通过硫酸二甲酯和浓缩KI反应来制备。据报道,碘和磷和甲醇反应也可合成碘甲烷。它和三苯基膦氯化铑(I)反应,生成铑(III)八面体配合物[RhlCl(CH3)(PPh3)2(ICH3)]。其与原子氯的气相反应动力学已过研究。该反应的绝对速率常数已有报道。
应用
碘甲烷(甲烷碘)可以用来制备稳定的中性次碘酸溶液和各种甲烷酯。
警示用语:
Danger
危险分类
Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Acute Tox. 4 Dermal - Aquatic Acute 1 - Aquatic Chronic 2 - Carc. 2 - Eye Dam. 1 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
89.8 °F - closed cup
闪点(°C)
32.1 °C - closed cup
个人防护装备
Faceshields, Gloves, Goggles
法规信息
新产品
Talanta, 211, 120725-120725 (2020-02-20)
This work designs the synthesis of a novel amino morpholine schiff base functionalized calix[4]arene cage (SCC), its deposition onto Quartz Crystal Microbalance (QCM) crystal surface, and usage for the selective detecting of formaldehyde (HCHO). The SCC modified QCM sensor has
Interaction of tris (triphenylphosphine) chlororhodium (I) with iodomethane, methylallyl, and allyl chloride.
J. Chem. Soc. Sect. A, 1733-1736 (1966)
Efficient methylation of carboxylic acids with potassium hydroxide/methyl sulfoxide and iodomethane.
Synthetic Communications, 31(14), 2177-2183 (2001)
Iodomethane oxidation by dimethyldioxirane: a new route to hypoiodous acid and iodohydrines.
Organic Letters, 1(13), 2125-2128 (1999)
Concise Encyclopedia Chemistry, 649-649 (1994)
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