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应用
Methylhydrazine can be used:
- In the synthesis of epoxides containing tetrasubstituted trifluoromethylated carbon center by the aerobic epoxidation of β,β-disubstituted enones.
- As a starting material along with 2-(methyl, phenyl or styryl)chromones for the synthesis of 3-(2-benzyloxy-6-hydroxyphenyl)-5-(methyl, phenyl or styryl)pyrazoles.
- As a starting material for one-step synthesis of [1,2]diazepino[4,5-b]indole derivatives by reacting with pyranoindolones.
警示用语：
Danger
危险分类
Acute Tox. 1 Inhalation - Acute Tox. 2 Dermal - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
17.6 °F - closed cup
闪点(°C)
-8 °C - closed cup
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
新产品
One-step synthesis of [1, 2] diazepino [4, 5-b] indole derivatives from the reaction of pyranoindolones with methylhydrazine
Hatzimimikou D, et al.
Synlett, 2008(12), 1773-1776 (2008)
Synthesis of 3-(2-benzyloxy-6-hydroxyphenyl)-1-methylpyrazoles by the reaction of chromones with methylhydrazine
Pinto DCGA, et al.
Journal of Heterocyclic Chemistry, 37(6), 1629-1634 (2000)
C P Siegers et al.
Cancer letters, 65(3), 245-249 (1992-08-31)
Iron-enriched diets caused an increase of tumor rate in two models of dimethylhydrazine(DMH)-induced colon tumorigenesis in mice. The effect was independent of the time the iron-diet was fed, i.e. during DMH-treatment or following the DMH-treatment period. The increase of tumor
M Gamberini et al.
Carcinogenesis, 19(1), 147-155 (1998-02-24)
Several hydrazine derivatives (HD) tested so far have pharmacological activities, but many also have toxic side effects, including carcinogenesis. Their toxicity has been ascribed to carbocations (via formation of azoxy intermediates), alkyl radicals or reactive oxygen species. Cytotoxicity and transformation
Christel Nonnenberg et al.
Physical chemistry chemical physics : PCCP, 10(30), 4383-4392 (2008-07-26)
The complications during flight 510 of the Ariane Project were ascribed to problems in the upper stage engine that employs the bipropellant monomethylhydrazine (MMH) and nitrogen tetroxide (NTO). This has led to the question what conditions or reactions possibly cause
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