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等级
for GC derivatization
质量水平
蒸汽压
0.06 psi ( 20 °C)
检测方案
≥97.0% (GC)
质量
LiChropur™
反应适用性
reagent type: derivatization reagent
reaction type: Acylations
技术
gas chromatography (GC): suitable
折射率
n20/D 1.424 (lit.)
bp
60-61 °C/7 mmHg (lit.)
密度
1.007 g/mL at 25 °C (lit.)
储存温度
2-8°C
SMILES字符串
CCCCCCOC(Cl)=O
InChI
1S/C7H13ClO2/c1-2-3-4-5-6-10-7(8)9/h2-6H2,1H3
InChI key
KIWBRXCOTCXSSZ-UHFFFAOYSA-N
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一般描述
Hexyl chloroformate belongs to the class of chloroformates. It is widely used in the derivatization of highly hydrophilic compounds to hexyl esters, carbonates and carbamates.
应用
Hexyl chloroformate may be used as a derivatizing reagent for the quantification of antiepileptic drugs, cathinones, amphetamine-like stimulants and other new psychoactive substances in biological samples using gas chromatography coupled to mass spectrometry (GC-MS).
法律信息
LiChropur is a trademark of Merck KGaA, Darmstadt, Germany
警示用语：
Danger
危险分类
Acute Tox. 3 Oral - Skin Corr. 1B
WGK
WGK 3
闪点(°F)
closed cup
闪点(°C)
closed cup
法规信息
新产品
Gabapentin, Pregabalin and Vigabatrin quantification in human serum by GC--MS after hexyl chloroformate derivatization
Hlozek T, et al.
Journal of Analytical Toxicology, 40(9), 749-753 (2016)
Determination of trace amounts of highly hydrophilic compounds in water by direct derivatization and gas chromatography?mass spectrometry
Minero C, et al.
Fresenius Journal of Analytical Chemistry, 350(6), 403-409 (1994)
Stacy D Brown et al.
Forensic science international, 171(2-3), 142-150 (2006-12-13)
A solid-phase microextraction-gas chromatographic-mass spectrometric (SPME-GC-MS) method has been developed and validated for measuring four club drugs in human urine. These drugs include gamma-hydroxybutyrate (GHB), ketamine (KET), methamphetamine (MAMP), and methylenedioxymethamphetamine (MDMA). These drugs are referred to as 'club drugs'
Rapid and simple procedure for the determination of cathinones, amphetamine-like stimulants and other new psychoactive substances in blood and urine by GC--MS
Mercieca G, et al.
Journal of Pharmaceutical and Biomedical Analysis, 149, 494-501 (2018)
Chloroformates in gas chromatography as general purpose derivatizing agents
Husek P
Journal of Chromatography. B, Biomedical Sciences and Applications, 717(1-2), 57-91 (1998)
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