所有图片(1)
别名:
(+)-MTPA, Mosher 酸
线性分子式:
C6H5C(OCH3)(CF3)CO2H
CAS号:
分子量:
234.17
Beilstein:
3591560
EC 号:
MDL编号:
UNSPSC代码:
12000000
PubChem化学物质编号:
NACRES:
NA.22
推荐产品
等级
for chiral derivatization
质量水平
检测方案
≥99.0% (T)
≥99.0%
形式
solid
旋光性
[α]20/D +73±1°, c = 2% in methanol
光学纯度
enantiomeric ratio: ≥99.5:0.5 (GC)
质量
LiChropur™
技术
HPLC: suitable
折射率
n20/D 1.473 (lit.)
bp
105-107 °C/1 mmHg (lit.)
mp
46-49 °C (lit.)
密度
1.344 g/mL at 25 °C (lit.)
储存温度
2-8°C
SMILES字符串
CO[C@@](C(O)=O)(c1ccccc1)C(F)(F)F
InChI
1S/C10H9F3O3/c1-16-9(8(14)15,10(11,12)13)7-5-3-2-4-6-7/h2-6H,1H3,(H,14,15)/t9-/m1/s1
InChI key
JJYKJUXBWFATTE-SECBINFHSA-N
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警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
WGK
WGK 3
闪点(°F)
closed cup
闪点(°C)
closed cup
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
J Gal
Journal of pharmaceutical sciences, 66(2), 169-172 (1977-02-01)
Amphetamine and eight related compounds were reacted with the chiral acylating reagent (-)-alpha-methoxy-alpha-(trifluoromethyl)phenylacetyl chloride to obtain, in each case, two diastereomeric amide derivatives. GLC conditions were found for the separation of the diastereomers in seven of the nine cases studied.
Michael North
Principles and Applications of Stereochemistry, 112-112 (1998)
D.R. Knapp
Handbook of Analytical Derivatization Reactions, 411-411 (1979)
A new chiral reagent for the determination of nantiomeric purity and absolute configuration of certain substituted -arylethylamines.
L R Pohl et al.
Journal of medicinal chemistry, 16(5), 475-479 (1973-05-01)
S. Yamagichi et al.
Asymmetric Synthesis, 1, 128-128 (1983)
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