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Merck
CN

648531

Sigma-Aldrich

N,N-二甲基甲酰胺

suitable for HPLC, ≥99.9%

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别名:
DMF, NSC 5356
线性分子式:
HCON(CH3)2
CAS号:
分子量:
73.09
Beilstein:
605365
EC 号:
MDL编号:
UNSPSC代码:
12190000
PubChem化学物质编号:

蒸汽密度

2.5 (vs air)

质量水平

蒸汽压

2.7 mmHg ( 20 °C)

检测方案

≥99.9%

形式

liquid

自燃温度

833 °F

expl. lim.

15.2 %

技术

HPLC: suitable

杂质

≤0.030% water

蒸发残留物

≤0.0005%

折射率

n20/D 1.430 (lit.)

bp

153 °C (lit.)

mp

−61 °C (lit.)

密度

0.944 g/mL (lit.)

吸光度

0.010 at 340 nm
0.010 at 400 nm
0.05 at 310 nm
0.10 at 295 nm
0.30 at 275 nm
1.00 at 270 nm

应用

food and beverages

SMILES字符串

[H]C(=O)N(C)C

InChI

1S/C3H7NO/c1-4(2)3-5/h3H,1-2H3

InChI key

ZMXDDKWLCZADIW-UHFFFAOYSA-N

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相关类别

一般描述

N,N-Dimethylformamide (DMF) is the commonly employed solvent for chemical reactions. DMF is a useful solvent employed for the isolation of chlorophyll from plant tissues. It is widely employed reagent in organic synthesis. It plays multiple roles in various reactions such as solvent, dehydrating agent, reducing agent as well as catalyst. It is a multipurpose building block for the synthesis of compounds containing O, -CO, -NMe2, -CONMe2, -Me, -CHO as functional groups. Dielectric relaxation experiments on DMF have been conducted between 238.15K and 338.15K. The thermophysical properties of the molecular interactions between DMF and the ionic liquids, ammonium salts and imidazolium salts have been studied. The characteristics of solute-solvent interactions between ammonium nitrate and DMF have been investigated.

应用

多种疏水性有机化合物的溶剂。

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警示用语:

Danger

危险分类

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Eye Irrit. 2 - Flam. Liq. 3 - Repr. 1B

WGK

WGK 2

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

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Synthesis and electrochemical characterization of aPEO-based polymer electrolytes.
Rodrigues LC, et al.
Journal of Solid State Electrochemistry, 16(4), 1623-1629 (2012)
Measurements and molecular interactions for N,N-dimethylformamide with ionic liquid mixed solvents.
Attri P, et al.
The Journal of Physical Chemistry B, 114(18), 6126-6133 (2010)
The dynamics of liquid formamide, N-methylformamide, N,N-dimethylformamide, and N,N-dimethylacetamide. A dielectric relaxation study.
Barthel J, et al.
Journal of Molecular Liquids, 98, 51-69 (2002)
Volumetric properties of ammonium nitrate in N,N-dimethylformamide.
Vranes M, et al.
The Journal of Chemical Thermodynamics, 54, 245-249 (2012)
W P Inskeep et al.
Plant physiology, 77(2), 483-485 (1985-02-01)
We found inconsistencies in the commonly used data for chlorophyll analysis in 80% acetone. Recently developed extinction coefficients for chlorophyll b in N,N-dimethylformamide (DMF) based on values from 80% acetone are low as a result of these inconsistencies. We determined

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