64258
甲基膦酸二甲酯
purum, ≥97.0% (GC)
别名:
Dimethoxymethyl phosphine oxide, Fyrol DMMP, Methanephosphonic acid dimethyl ester, NSC 62240, Reoflam DMMP
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关于此项目
线性分子式:
CH3P(O)(OCH3)2
化学文摘社编号:
分子量:
124.08
UNSPSC Code:
12352108
NACRES:
NA.22
PubChem Substance ID:
EC Number:
212-052-3
Beilstein/REAXYS Number:
878263
MDL number:
Assay:
≥97.0% (GC)
InChI key
VONWDASPFIQPDY-UHFFFAOYSA-N
InChI
1S/C3H9O3P/c1-5-7(3,4)6-2/h1-3H3
SMILES string
COP(C)(=O)OC
vapor pressure
<0.1 mmHg ( 20 °C)
grade
purum
assay
≥97.0% (GC)
reaction suitability
reaction type: C-C Bond Formation
Quality Level
bp
181 °C (lit.)
density
1.145 g/mL at 25 °C (lit.)
functional group
phosphonate
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Application
Dimethyl methylphosphonate (DMPP) is generally used as a model compound for catalytic degradation studies due to its structural similarity to the organophosphorus compounds used in chemical warfare agents, pesticides and herbicides.
Used to test SXFA-coated SAW chemical sensors for organophosphorous compound detection
Used as a chemical agent simulant for testing of protective performance of PSS membranes and functionalized sorbent membranes
Reactant for photocatalytic oxidation
Additive for synthesis of:
Used as a chemical agent simulant for testing of protective performance of PSS membranes and functionalized sorbent membranes
Reactant for photocatalytic oxidation
Additive for synthesis of:
- Flame retardant high phosphorous containing unsaturated polyester resin
- UV-cured epoxy acrylate / microencapsulated phase change material
Other Notes
简便的 Wittig-Horner 试剂
signalword
Danger
hcodes
Hazard Classifications
Eye Irrit. 2 - Muta. 1B - Repr. 2
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
156.2 °F - closed cup
flash_point_c
69 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
监管及禁止进口产品
此项目有
Study of the catalytic destruction of dimethyl methylphosphonate (DMMP): oxidation over molybdenum (110)
Smentkowski VS, et al.
The Journal of Physical Chemistry, 92(22), 6351-6357 (1988)
Enhanced photocatalytic degradation of dimethyl methylphosphonate in the presence of low-frequency ultrasound
Chen Y-C, et al.
Photochemical & Photobiological Sciences : Official Journal of the European Photochemistry Association and the European Society for Photobiology, 2(6), 694-698 (2003)
M. Mikolajczyk et al.
The Journal of Organic Chemistry, 43, 473-473 (1978)
Adsorption and decomposition of dimethyl methylphosphonate on TiO2
Rusu CN and Yates JT
The Journal of Physical Chemistry B, 104(51), 12292-12298 (2000)
Lingtao Kong et al.
The Analyst, 135(2), 368-374 (2010-01-26)
Fabrication of hybridized single-walled carbon nanotube (SWNT) device based on novel sensing material N-4-Hexafluoroisopropanolphenyl-1-pyrenebutyramide (HFIPP) via facile approach has been reported for the first time. Considered that strong hydrogen-bonding can be formed between HFIPP and dimethyl methylphosphonate (DMMP) (simulant of
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