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Merck
CN

62136

(+)-反式-柠檬烯 1,2-环氧化物

analytical standard

别名:

(+)-反式-对-薄荷-1,8-二烯 1,2-环氧化物, (1S,2R,4R)-4-异丙烯基-1-甲基-1-环己烯 1,2-环氧化物, (1S,4R)-1,2-环氧-对-薄荷-8-烯

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关于此项目

经验公式(希尔记法):
C10H16O
化学文摘社编号:
分子量:
152.23
UNSPSC Code:
85151701
NACRES:
NA.24
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
80940
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InChI

1S/C10H16O/c1-7(2)8-4-5-10(3)9(6-8)11-10/h8-9H,1,4-6H2,2-3H3/t8-,9-,10+/m1/s1

SMILES string

CC([C@@H]1CC[C@@]2(C)[C@@](O2)([H])C1)=C

InChI key

CCEFMUBVSUDRLG-BBBLOLIVSA-N

grade

analytical standard

assay

≥95.0% (sum of enantiomers, GC)

optical activity

[α]20/D +90±2°, neat

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable, gas chromatography (GC): suitable

refractive index

n20/D 1.466

density

0.930 g/mL at 20 °C (lit.)

application(s)

food and beverages

format

neat

storage temp.

2-8°C

Application

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

存储类别

10 - Combustible liquids

wgk

WGK 3

flash_point_f

149.0 °F - closed cup

flash_point_c

65 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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J S Prescott-Mathews et al.
Toxicology and applied pharmacology, 157(1), 60-67 (1999-05-18)
Methyl tert-butyl ether (MTBE), a fuel additive blended into unleaded gasoline, decreases emissions of selected air pollutants. Exposure to MTBE causes a low incidence of renal tumors in male, but not female, F-344 rats. A number of chemicals that cause
Maliha Uroos et al.
The Journal of organic chemistry, 75(24), 8465-8470 (2010-11-23)
A total synthesis of (+)-cymbodiacetal (1) has been completed from (R)-(+)-limonene oxide using a hetero-Diels-Alder cycloaddition as a key step. The key Diels-Alder cycloaddition proceeds with endo-selectivity (2:1, endo/exo) in quantitative yield, and the two diastereomeric spirochroman products are isolable
L D Lehman-McKeeman et al.
Toxicology and applied pharmacology, 116(2), 170-176 (1992-10-01)
The rate-limiting step in chemically induced, male rat-specific hyaline droplet nephropathy is the reversible binding of a xenobiotic to alpha 2u-globulin. In this study, equilibrium saturation binding experiments were conducted to evaluate the in vitro binding of d-limonene-1,2-oxide (dLO) and
Juan Ramón Avilés Moreno et al.
Physical chemistry chemical physics : PCCP, 11(14), 2459-2467 (2009-03-28)
S-(-)-Limonene oxide (4-isopropenyl-1-methyl-7-oxabicyclo[4.1.0]heptane) is a secondary metabolite and an atmospheric pollutant product of oxidation of other terpenes, such as limonene and alpha-pinene, among others. For the first time, a theoretical study of the molecular structure and a theoretical and experimental
Christopher M Byrne et al.
Journal of the American Chemical Society, 126(37), 11404-11405 (2004-09-16)
The alternating copolymerization of (R)- or (S)-limonene oxide and CO2 using beta-diiminate zinc acetate catalysts is reported. At 100 psi CO2 and 25 degrees C, the catalyst exhibits a high selectivity for the trans isomer and produces regioregular polycarbonate. The

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