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Merck
CN

62136

Supelco

(+)-反式-柠檬烯 1,2-环氧化物

analytical standard

别名:

(+)-反式-对-薄荷-1,8-二烯 1,2-环氧化物, (1S,2R,4R)-4-异丙烯基-1-甲基-1-环己烯 1,2-环氧化物, (1S,4R)-1,2-环氧-对-薄荷-8-烯

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About This Item

经验公式(希尔记法):
C10H16O
CAS号:
分子量:
152.23
Beilstein:
80940
MDL编号:
UNSPSC代码:
85151701
PubChem化学物质编号:
NACRES:
NA.24

等级

analytical standard

方案

≥95.0% (sum of enantiomers, GC)

旋光性

[α]20/D +90±2°, neat

保质期

limited shelf life, expiry date on the label

技术

HPLC: suitable
gas chromatography (GC): suitable

折射率

n20/D 1.466

密度

0.930 g/mL at 20 °C (lit.)

应用

food and beverages

包装形式

neat

储存温度

2-8°C

SMILES字符串

CC([C@@H]1CC[C@@]2(C)[C@@](O2)([H])C1)=C

InChI

1S/C10H16O/c1-7(2)8-4-5-10(3)9(6-8)11-10/h8-9H,1,4-6H2,2-3H3/t8-,9-,10+/m1/s1

InChI key

CCEFMUBVSUDRLG-BBBLOLIVSA-N

应用

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

储存分类代码

10 - Combustible liquids

WGK

WGK 3

闪点(°F)

149.0 °F - closed cup

闪点(°C)

65 °C - closed cup

个人防护装备

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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M J van der Werf et al.
Journal of bacteriology, 180(19), 5052-5057 (1998-09-28)
An epoxide hydrolase from Rhodococcus erythropolis DCL14 catalyzes the hydrolysis of limonene-1,2-epoxide to limonene-1,2-diol. The enzyme is induced when R. erythropolis is grown on monoterpenes, reflecting its role in the limonene degradation pathway of this microorganism. Limonene-1,2-epoxide hydrolase was purified
J W Regan et al.
Xenobiotica; the fate of foreign compounds in biological systems, 10(12), 859-861 (1980-12-01)
1. The metabolism of limonene-1,2-epoxide was studied following intraperitoneal injection in rats and in rat liver homogenates. 2. Limonene-1,2-glycol was the only neutral metabolite detected. Major limonene metabolites, p-mentha-2,8-dien-1-alpha and -beta-ol and p-mentha-1,8-dien-6-alpha and -beta-ol were not observed. 3. Limonene-1,2-epoxide
L D Lehman-McKeeman et al.
Toxicology and applied pharmacology, 103(3), 539-548 (1990-05-01)
A diverse group of chemicals cause a male rat-specific nephrotoxicity in which alpha 2u-globulin accumulates in renal lysosomes. It has been suggested that these chemicals bind to the protein and decrease its degradation by lysosomal proteinases. To test this hypothesis
Christopher M Byrne et al.
Journal of the American Chemical Society, 126(37), 11404-11405 (2004-09-16)
The alternating copolymerization of (R)- or (S)-limonene oxide and CO2 using beta-diiminate zinc acetate catalysts is reported. At 100 psi CO2 and 25 degrees C, the catalyst exhibits a high selectivity for the trans isomer and produces regioregular polycarbonate. The
Juan Ramón Avilés Moreno et al.
Physical chemistry chemical physics : PCCP, 11(14), 2459-2467 (2009-03-28)
S-(-)-Limonene oxide (4-isopropenyl-1-methyl-7-oxabicyclo[4.1.0]heptane) is a secondary metabolite and an atmospheric pollutant product of oxidation of other terpenes, such as limonene and alpha-pinene, among others. For the first time, a theoretical study of the molecular structure and a theoretical and experimental

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