56257
二茂铁硼酸
derivatization grade (HPLC), LiChropur™, ≥97.0% (HPLC)
别名:
(Boronocyclopentadienyl)cyclopentadienyl iron, NSC 119337
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关于此项目
经验公式（希尔记法）:
C10H11BFeO2
化学文摘社编号:
分子量:
229.85
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352200
EC Number:
235-272-1
MDL number:
InChI key
HHGAJIKAUQWFKH-UHFFFAOYSA-N
InChI
1S/C5H6BO2.C5H5.Fe/c7-6(8)5-3-1-2-4-5;1-2-4-5-3-1;/h1-4,7-8H;1-5H;
SMILES string
[Fe].[CH]1[CH][CH][CH][CH]1.OB(O)[C]2[CH][CH][CH][CH]2
grade
derivatization grade (HPLC)
assay
≥97.0% (HPLC)
quality
LiChropur™
reaction suitability
reagent type: catalyst
core: iron
technique(s)
HPLC: suitable
mp
145-150 °C (dec.) (lit.)
Quality Level
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Application
用于油菜素甾醇测定的衍生化试剂
Redox-acitce electrochemical probe to monitor interactions involving sugars
Reactant involved in:
Reactant involved in:
- Synthesis of ferrocene-appended subporphyrins for electrochemical property studies
- Synthesis of catalysts for polymerization of olefins
- Suzuki-coupling reaction with organic triflates
- Catalytic ortho-lithiation
Packaging
Bottomless glass bottle. Contents are inside inserted fused cone.
Legal Information
LiChropur is a trademark of Merck KGaA, Darmstadt, Germany
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Keiji Gamoh, K., et al.
Journal of Chromatography A, 515, 227-231 (1990)
Artur Kasprzak et al.
Carbohydrate polymers, 198, 294-301 (2018-08-11)
Interactions of select boric acid derivatives with β-cyclodextrin were investigated. All products were obtained employing the grinding-induced mechanochemical approach. It was found that phenylboronic acid, benzoxaborole and boric acid form non-covalent, hydrogen bonding-based systems with β-cyclodextrin, whereas catechol and pinacol
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