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Merck
CN

49497

Supelco

硫酸二甲酯

for GC derivatization, LiChropur, ≥99.0% (GC)

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别名:
二甲基硫酸酯
线性分子式:
(CH3O)2SO2
CAS号:
分子量:
126.13
Beilstein:
635994
EC 号:
MDL编号:
UNSPSC代码:
12000000
PubChem化学物质编号:
NACRES:
NA.22

等级

for GC derivatization

质量水平

蒸汽密度

4.3 (vs air)

蒸汽压

0.7 mmHg ( 25 °C)

检测方案

≥99.0% (GC)

自燃温度

923 °F

质量

LiChropur

反应适用性

reagent type: derivatization reagent
reaction type: Alkylations

技术

gas chromatography (GC): suitable

折射率

n20/D 1.386 (lit.)
n20/D 1.387

bp

188 °C (lit.)

mp

−32 °C (lit.)

密度

1.333 g/mL at 25 °C (lit.)

SMILES字符串

COS(=O)(=O)OC

InChI

1S/C2H6O4S/c1-5-7(3,4)6-2/h1-2H3

InChI key

VAYGXNSJCAHWJZ-UHFFFAOYSA-N

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应用

Dimethyl sulfate may be used as a derivatization reagent for the esterification reaction in the determination of pharmaceuticals by automated aqueous derivatization solid-phase microextraction (SPME) coupled with gas chromatography/mass spectrometry (GC/MS).

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法律信息

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

警示用语:

Danger

危险分类

Acute Tox. 2 Inhalation - Acute Tox. 3 Oral - Carc. 1B - Eye Dam. 1 - Muta. 2 - Skin Corr. 1B - Skin Sens. 1

WGK

WGK 3

闪点(°F)

closed cup

闪点(°C)

closed cup

法规信息

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M J Cardador et al.
Journal of chromatography. B, Analytical technologies in the biomedical and life sciences, 878(21), 1824-1830 (2010-06-15)
Haloacetic acids (HAAs) are water disinfection byproducts (DBPs) formed by the reaction of chlorine oxidizing compounds with natural organic matter in water containing bromine. HAAs are second to trihalomethanes as the most commonly detected DBPs in surface drinking water and
Siming Huang et al.
Talanta, 136, 198-203 (2015-02-24)
An automated aqueous derivatization solid-phase microextraction (SPME) coupled with a gas chromatography/mass spectrometry (GC/MS) method was developed for simultaneous determination of eight pharmaceuticals in water samples. Dimethyl sulfate and tetrabutylammonium hydrogen sulfate were selected as derivatization and activation reagents for

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