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等级
purum
方案
≥97.0% (GC)
折射率
n20/D 1.507 (lit.)
n20/D 1.509
沸点
187-189 °C (lit.)
密度
1.137 g/mL at 20 °C (lit.)
SMILES字符串
CC(=O)c1ccccc1F
InChI
1S/C8H7FO/c1-6(10)7-4-2-3-5-8(7)9/h2-5H,1H3
InChI key
QMATYTFXDIWACW-UHFFFAOYSA-N
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应用
2′-Fluoroacetophenone may be used as starting reagent in the synthesis of ascididemin.
警示用语：
Warning
危险声明
预防措施声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2
储存分类代码
10 - Combustible liquids
WGK
WGK 3
闪点(°F)
143.6 °F - closed cup
闪点(°C)
62 °C - closed cup
个人防护装备
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
The enantioselective reduction of 2'-fluoroacetophenone utilizing a simplified CBS-reduction procedure.
Garrett CE, et al.
Tetrahedron Asymmetry, 13(13), 1347-1349 (2002)
Ida Nymann Petersen et al.
Chemical communications (Cambridge, England), 48(72), 9092-9094 (2012-08-07)
A new and convergent synthesis of ascididemin is presented. Using an anionic cascade ring closure as the key step, this natural product is obtained in 45% overall yield in just 6 steps starting from 2'-fluoroacetophenone. This new approach was extended
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