等级
analytical standard
质量水平
检测方案
≥99.5% (sum of enantiomers, GC)
旋光性
[α]20/D +62±1°, neat
保质期
limited shelf life, expiry date on the label
技术
HPLC: suitable
gas chromatography (GC): suitable
折射率
n20/D 1.462
bp
63-65 °C/13 mmHg (lit.)
mp
5-7 °C (lit.)
密度
0.945 g/mL at 20 °C (lit.)
应用
cleaning products
cosmetics
flavors and fragrances
food and beverages
personal care
格式
neat
SMILES字符串
CC1(C)[C@@H]2CC[C@@](C)(C2)C1=O
InChI
1S/C10H16O/c1-9(2)7-4-5-10(3,6-7)8(9)11/h7H,4-6H2,1-3H3/t7-,10+/m1/s1
InChI key
LHXDLQBQYFFVNW-XCBNKYQSSA-N
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应用
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
其他说明
高纯度 (+)-葑酮；酮官能可以多种方式转化
储存分类代码
10 - Combustible liquids
WGK
WGK 2
闪点(°F)
150.8 °F - closed cup
闪点(°C)
66 °C - closed cup
个人防护装备
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
P. Gosselin et al.
Tetrahedron Letters, 31, 3151-3151 (1990)
L.A. Paquette et al.
The Journal of Organic Chemistry, 57, 3965-3965 (1992)
Santiago de la Moya Cerero et al.
The Journal of organic chemistry, 68(4), 1451-1458 (2003-02-15)
Valuable chiral sources of C(10)-substituted camphors and C(10)-substituted fenchones can be straightforwardly obtained by treatment of an appropriate, easily obtainable, camphor- or fenchone-derived 2-methylenenorbornan-1-ol with an electrophilic reagent. The process takes place via a tandem regioselective carbon-carbon double-bond addition/stereocontrolled Wagner-Meerwein
Mitsuo Miyazawa et al.
Biological & pharmaceutical bulletin, 29(12), 2354-2358 (2006-12-05)
The in vitro metabolism of (+)-fenchone was examined in human liver microsomes and recombinant enzymes. Biotransformation of (+)-fenchone was investigated by gas chromatography-mass spectrometry. (+)-Fenchone was found to be oxidized to 6-exo-hydroxyfenchone, 6-endo-hydroxyfenchone and 10-hydroxyfenchone by human liver microsomal P450
Dirk W Lachenmeier et al.
Journal of agricultural and food chemistry, 56(9), 3073-3081 (2008-04-19)
Thirteen samples of authentic absinthe dating from the preban era (i.e., prior to 1915) were analyzed for parameters that were hypothesized as contributing to the toxicity of the spirit, including naturally occurring herbal essences (thujone, pinocamphone, fenchone), methanol, higher alcohols
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