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等级
analytical standard
质量水平
方案
≥99.0% (sum of enantiomers, GC)
旋光性
[α]20/D +11.0±0.5°, c = 10% in ethanol
保质期
limited shelf life, expiry date on the label
技术
HPLC: suitable
gas chromatography (GC): suitable
沸点
201-202 °C (lit.)
mp
43-46 °C
包装形式
neat
SMILES字符串
CC1(C)[C@H]2CC[C@](C)(C2)[C@H]1O
InChI
1S/C10H18O/c1-9(2)7-4-5-10(3,6-7)8(9)11/h7-8,11H,4-6H2,1-3H3/t7-,8-,10+/m0/s1
InChI key
IAIHUHQCLTYTSF-OYNCUSHFSA-N
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应用
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
其他说明
手性结构单元
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
165.2 °F - closed cup
闪点(°C)
74 °C - closed cup
个人防护装备
Eyeshields, Gloves, type N95 (US)
A.A. van der Zeijden et al.
Synthesis, 847-847 (1996)
Y. Yuasa et al.
Tetrahedron, 48, 3473-3473 (1992)
R Croteau et al.
The Journal of biological chemistry, 263(30), 15449-15453 (1988-10-25)
The conversion of geranyl pyrophosphate to (-)-endo-fenchol is considered to proceed by the initial isomerization of the substrate to (-)-(3R)-linalyl pyrophosphate and the subsequent cyclization of this bound intermediate. Incubation of (1R)-[2-14C,1-3H]- and (1S)-[2-14C,1-3H]geranyl pyrophosphate with a preparation of (-)-endo-fenchol
Sergio Abbate et al.
Chirality, 21 Suppl 1, E242-E252 (2009-11-21)
The first well documented experiments of Near Infrared Vibrational Circular Dichroism (NIR-VCD) were performed around 1975. We review the thirty year history of NIR-VCD, encompassing both instrumental development and theoretical/computational methods that allow interpretation of experimental spectra, harvesting useful structural
M Miyazawa et al.
Xenobiotica; the fate of foreign compounds in biological systems, 37(9), 943-953 (2007-11-10)
The metabolism of (+)-fenchol was investigated in vitro using liver microsomes of rats and humans and recombinant cytochrome P450 (P450 or CYP) enzymes in insect cells in which human/rat P450 and NADPH-P450 reductase cDNAs had been introduced. The biotransformation of
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