44028
环己烯
analytical standard, ≥99.5% (GC)
别名:
四氢化苯
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关于此项目
经验公式（希尔记法）:
C6H10
化学文摘社编号:
分子量:
82.14
NACRES:
NA.24
PubChem Substance ID:
EC Number:
203-807-8
Beilstein/REAXYS Number:
906737
MDL number:
UNSPSC Code:
12141716
产品名称
环己烯, analytical standard, ≥99.5% (GC)
InChI
1S/C6H10/c1-2-4-6-5-3-1/h1-2H,3-6H2
InChI key
HGCIXCUEYOPUTN-UHFFFAOYSA-N
SMILES string
C1CCC=CC1
grade
analytical standard
vapor density
2.8 (vs air)
vapor pressure
160 mmHg ( 20 °C)
assay
≥99.5% (GC)
autoignition temp.
590 °F
shelf life
limited shelf life, expiry date on the label
contains
~0.01% 2,6-di-tert-butyl-4-methylphenol as stabilizer
expl. lim.
5 %
technique(s)
HPLC: suitable
gas chromatography (GC): suitable
refractive index
n20/D 1.446 (lit.)
n20/D 1.446
bp
83 °C (lit.)
mp
−104 °C (lit.)
density
0.811 g/mL at 25 °C (lit.)
application(s)
environmental
petroleum
format
neat
Quality Level
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signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Chronic 2 - Asp. Tox. 1 - Flam. Liq. 2
存储类别
3 - Flammable liquids
wgk
WGK 2
flash_point_f
1.4 °F
flash_point_c
-17 °C
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Amelia W Ray et al.
The journal of physical chemistry. A, 116(25), 6720-6730 (2012-05-29)
Earlier synchrotron photoionization mass spectrometry experiments suggested a prominent ring-opening channel in the OH-initiated oxidation of cyclohexene, based on comparison of product photoionization spectra with calculated spectra of possible isomers. The present work re-examines the OH + cyclohexene reaction, measuring
Hiroshi Nagase et al.
Bioorganic & medicinal chemistry letters, 22(15), 5071-5074 (2012-06-30)
To clarify the essential structures of an opioid κ receptor selective agonist, nalfurafine, for binding to the κ receptor, we designed and synthesized some nalfurafine derivatives and the decahydro(iminoethano)phenanthrene derivatives with a cyclohexene moiety as a surrogate for the phenol
Jan Lennard Wolf et al.
Physical chemistry chemical physics : PCCP, 13(23), 10952-10964 (2011-03-29)
The gas-phase ozonolysis of cyclic-alkenes (1-methyl-cyclohexene, methylene-cyclohexane, α-pinene, β-pinene) is studied with respect to the pressure dependent formation of secondary organic aerosol (SOA). We find that SOA formation is substantially suppressed at lower pressures for all alkenes under study. The
Oxidative decarboxylation of benzilic acid by a biomimetic iron(II) complex: evidence for an iron(IV)-oxo-hydroxo oxidant from O2.
Sayantan Paria et al.
Angewandte Chemie (International ed. in English), 50(47), 11129-11132 (2011-10-01)
Sylvain Dalençon et al.
The Journal of organic chemistry, 76(19), 8059-8063 (2011-08-26)
The asymmetric synthesis of novel cyclohexene nucleoside analogues 12 and 15 is described. An enantiospecific Diels-Alder reaction between (E,E)-diene 2 and (+)-5-(d-mentyloxy)-2(5H)-furanone 3 provided the cycloadduct isomer 4. Three additional steps yielded amine 8 allowing the constructions of the thymine
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