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安全信息

439142

Supelco

氯仿

suitable for HPLC, ≥99.8%, contains 0.5-1.0% ethanol as stabilizer

别名:

三氯甲烷

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About This Item

经验公式（希尔记法）:
CHCl3
CAS号:
67-66-3
分子量:
119.38
Beilstein:
1731042
MDL编号:
MFCD00000826
UNSPSC代码:
12190000
PubChem化学物质编号:
24867327
方案:
≥99.8%
技术:
HPLC: suitable
应用:
food and beverages
沸点:
60.5-61.5 °C (lit.)
蒸汽压:
160 mmHg ( 20 °C)

蒸汽密度

4.1 (vs air)

质量水平

100

蒸汽压

160 mmHg ( 20 °C)

方案

≥99.8%

表单

liquid

包含

0.5-1.0% ethanol as stabilizer

包装

PVC-coated bottle of 4, 4x4 L

技术

HPLC: suitable

杂质

<0.01% water

蒸发残留物

<0.0003%

颜色

APHA: ≤10

折射率

n20/D 1.445 (lit.)

沸点

60.5-61.5 °C (lit.)

mp

−63 °C (lit.)

密度

1.48 g/mL at 25 °C
1.492 g/mL at 25 °C (lit.)

痕量阳离子

Pb: ≤0.05 ppm

λ

H2O reference

紫外吸收

λ: 245 nm Amax: 1.00
λ: 255 nm Amax: 0.15
λ: 260 nm Amax: 0.15
λ: 270 nm Amax: 0.02
λ: 290-400 nm Amax: 0.01

应用

food and beverages

SMILES字符串

ClC(Cl)Cl

InChI

1S/CHCl3/c2-1(3)4/h1H

InChI key

HEDRZPFGACZZDS-UHFFFAOYSA-N

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相关类别

一般描述

Chloroform is a colorless, volatile chlorinated organic solvent whose vapors have a narcotic effect. It is susceptible to degradation with time, which can be suppressed by adding ethanol as a stabilizer. Since ethanol is added in higher concentration it leads to increase in polarity which may have a potential influence on some of the applications. Reports suggest that chloroform stabilized with ethanol reduces chances on creating artifacts during the chromatographic separation after extraction of anthracyclines from biological matrices.

应用

Chloroform was used as an organic phase in the methylene blue (MB) two-phase titration process for estimating the cationic surfactant content in high salinity brine.
It may be used as:
  • Solvent for electropolymerization.
  • Solvent for recrystallization.
  • Extractant in solvent extraction process.

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象形图

Skull and crossbonesHealth hazard
GHS06,GHS08

警示用语：

Danger

危险分类

Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Repr. 2 - Skin Irrit. 2 - STOT RE 1 Oral - STOT SE 3

靶器官

Central nervous system, Liver,Kidney

储存分类代码

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

WGK

WGK 3

闪点(°F)

does not flash

闪点(°C)

does not flash

法规信息

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分析证书(COA)

Lot/Batch Number
SHBQ1584
SHBQ9222
SHBP4461
SHBN0750
SHBL0432

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Solubility controlled electropolymerisation and study of the impact of regioregularity on the spectroelectrochemical properties of thin films of poly (3-octylthiophenes).
Jarosz T, et al.
Electrochimica Acta, 122, 66-71 (2014)
Leyu Cui et al.
Analytical chemistry, 86(22), 11055-11061 (2014-11-05)
The methylene blue (MB) two-phase titration method is a rapid and efficient method for determining the concentrations of anionic surfactants. The point at which the aqueous and chloroform phases appear equally blue is called Epton's end point. However, many inorganic
Traces of phosgene in chloroform: Consequences for extraction of anthracyclines.
Maudens KE, et al.
Journal of Chromatography. B, Biomedical Applications, 848(2), 384-390 (2007)
Eagleson M.
Concise Encyclopedia Chemistry, 216-216 (1994)
Analytical chemistry in a drop. Solvent extraction in a microdrop.
Liu H and Dasgupta PK.
Analytical Chemistry, 68(11), 1817-1821 (1996)
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