40263
N,N-二甲基甲酰胺二 叔丁基缩醛
technical, ≥90% (GC)
别名:
1,1-二叔丁氧基三甲胺, 1,1-双-叔-丁氧基-N,N-二甲基甲胺
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关于此项目
线性分子式:
(CH3)2NCH[OC(CH3)3]2
化学文摘社编号:
分子量:
203.32
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
253-222-7
Beilstein/REAXYS Number:
969629
MDL number:
产品名称
N,N-二甲基甲酰胺二 叔丁基缩醛, technical, ≥90% (GC)
InChI
1S/C11H25NO2/c1-10(2,3)13-9(12(7)8)14-11(4,5)6/h9H,1-8H3
InChI key
DBNQIOANXZVWIP-UHFFFAOYSA-N
SMILES string
CN(C)C(OC(C)(C)C)OC(C)(C)C
grade
technical
assay
≥90% (GC)
form
liquid
refractive index
n20/D 1.413 (lit.)
bp
56-57 °C/8 mmHg (lit.)
density
0.848 g/mL at 25 °C (lit.)
functional group
amine
ether
Quality Level
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Application
N,N-二甲基甲酰胺二-叔-丁基缩醛可用于制备以下物质：
- (S)-2-(1-叔-丁氧基羰基-2- {4- [2-（5-甲基-2-苯基恶唑-4-基）乙氧基]苯基}乙氨基）苯甲酸甲酯
- 3-O-叔-丁基吗啡
- 吡咯和吲哚羧酸的叔-丁酯
Other Notes
综述；叔-丁酯的合成。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
95.0 °F - closed cup
flash_point_c
35 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
U. Widmer
Synthesis, 135-135 (1983)
William B Mathews et al.
Journal of nuclear medicine : official publication, Society of Nuclear Medicine, 46(10), 1719-1726 (2005-10-06)
The goal of this study was to synthesize and evaluate in vivo the peroxisome proliferator-activated receptor-gamma (PPARgamma) agonist (11)C-GW7845 ((S)-2-(1-carboxy-2-{4-[2-(5-methyl-2-phenyloxazol-4-yl)ethoxy]phenyl}ethylamino)benzoic acid methyl ester) ((11)C-compound 1). PPARgamma is a member of a family of nuclear receptors that plays a central role
E Mohacsi et al.
Journal of medicinal chemistry, 25(10), 1264-1266 (1982-10-01)
3-O-tert-Butylmorphine (5) was prepared from 6-O-acetylmorphine (3) via alkylation with N,N-dimethylformamide di-tert-butyl acetal, followed by hydrolytic removal of the 3-(dimethylamino)-2-propenoate group. The same process was used to prepare the tert-butyl ether of levorphanol (6), (-)-3-tert-butoxy-N-methylmorphinan (8). Both 5 and 8
Convenient synthesis of pyrrole-and indolecarboxylic acid tert-butylesters.
Ludwig J and Lehr M.
Synthetic Communications, 34(20), 3691-3695 (2004)
R.F. Abdulla et al.
Tetrahedron, 35, 1675-1675 (1979)
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