40220
4,4′-二甲基-2,2′-联吡啶
≥99.0%
别名:
2,2′-二(γ-甲基吡啶), 4,4′-二甲基-2,2′-二吡啶
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关于此项目
经验公式（希尔记法）:
C12H12N2
化学文摘社编号:
分子量:
184.24
UNSPSC Code:
41116105
NACRES:
NA.21
PubChem Substance ID:
EC Number:
214-483-2
Beilstein/REAXYS Number:
128995
MDL number:
产品名称
4,4′-二甲基-2,2′-联吡啶, ≥99.0%
InChI key
NBPGPQJFYXNFKN-UHFFFAOYSA-N
InChI
1S/C12H12N2/c1-9-3-5-13-11(7-9)12-8-10(2)4-6-14-12/h3-8H,1-2H3
SMILES string
Cc1ccnc(c1)-c2cc(C)ccn2
assay
≥99.0% (NT)
≥99.0%
form
solid
technique(s)
UV/Vis spectroscopy: suitable
mp
169-174 °C (lit.)
171-173 °C
Quality Level
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Application
It was used as a ligand in a study done to understand the photosubstitution in Tris chelate complexes of Ruthenium (II).
General description
4,4′-Dimethyl-2,2′-dipyridyl is a monondentate ligand.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Photosubstitution in tris chelate complexes of ruthenium (II) containing the ligands 2, 2'-bipyrazine, 2, 2'-bipyrimidine, 2, 2'-bipyridine, and 4, 4'-dimethyl-2, 2'-bipyridine: energy gap control.
Ross, Helen B., et al.
Inorganic Chemistry, 28, 1013-1021 (1989)
Yang-Hui Luo et al.
Dalton transactions (Cambridge, England : 2003), 43(44), 16937-16942 (2014-10-11)
A new iron(II) complex based on the 4,4'-dimethyl-2,2'-bipyridine ligand [Fe(4,4'-dmbpy)3(ClO4)(SCN)·3H2O (1·3H2O)] has been prepared and characterized. Structural studies and Hirshfeld surface analysis for complex 1·3H2O at three different temperatures (300, 240 and 130 K) are described. The UV-vis absorption spectrum
Wendell Ho-Tin Law et al.
ChemMedChem, 9(6), 1316-1329 (2014-03-20)
We present a new class of phosphorescent cyclometalated iridium(III) bipyridyl-phenylenediamine complexes [Ir(N^C)2 (bpy-DA)](PF6 ) (bpy-DA=4-(N-(2-amino-5-methoxyphenyl)aminomethyl)-4'-methyl-2,2'-bipyridine; HN^C=2-(2,4-difluorophenyl)pyridine (Hdfppy) (1 a), 2-phenylpyridine (Hppy) (2 a), 2-phenylquinoline (Hpq) (3 a), 2-phenylcinchoninic acid methyl ester (Hpqe) (4 a)) and their triazole counterparts [Ir(N^C)2 (bpy-T)](PF6
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