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等级
ACS reagent
质量水平
蒸汽密度
3 (vs air)
蒸汽压
1 mmHg ( 13.6 °C)
1.5 mmHg ( 20 °C)
方案
≥99%
表单
liquid
自燃温度
572 °F
expl. lim.
10 %, 100 °F
杂质
≤0.075 meq/g acids and esters
≤0.1% carbonyl (as HCHO)
≤0.5% water
蒸发残留物
≤0.003%
颜色
APHA: ≤30
折射率
n20/D 1.409 (lit.)
沸点
136-138 °C (lit.)
mp
−78 °C (lit.)
溶解性
water: soluble 22.8 g/L at 25 °C
密度
0.811 g/mL at 25 °C (lit.)
SMILES字符串
CCCCCO
InChI
1S/C5H12O/c1-2-3-4-5-6/h6H,2-5H2,1H3
InChI key
AMQJEAYHLZJPGS-UHFFFAOYSA-N
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一般描述
1-戊醇是单羟基醇。它是一种无色液体,具有特有的气味。由于其具有替代汽油和柴油的特性,因此对其燃烧性能进行了研究。使用离子交换树脂作为催化剂,在间歇式反应器中,在 423K 下,在液相中将 1-戊醇转化为二-正-戊基醚(DNPE)。
应用
使用硝酸铈铵(CAN)通过氧化将 1-戊醇用于合成 2-甲基四氢呋喃。
警示用语:
Danger
危险分类
Acute Tox. 4 Inhalation - Eye Dam. 1 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
3 - Flammable liquids
WGK
WGK 1
闪点(°F)
120.2 °F - closed cup
闪点(°C)
49 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
Liquid-phase dehydration of 1-octanol, 1-hexanol and 1-pentanol to linear symmetrical ethers over ion exchange resins.
Casas C, et al.
Applied Catalysis A: General, 396(1), 129-139 (2011)
Oxidation of organic compounds with cerium (IV). IX. Formation of 2-methyltetrahydrofuran by oxidation of 1-pentanol.
Trahanovsky WS, et al.
Tetrahedron Letters, 10(30), 2501-2504 (1969)
Solvothermal synthesis of submillimeter ultralong hydroxyapatite nanowires using a calcium oleate precursor in a series of monohydroxy alcohols.
Jiang YY, et al.
Ceramics International, 41(4), 6098-6102 (2015)
Experimental and detailed kinetic modeling study of 1-pentanol oxidation in a JSR and combustion in a bomb.
Togbe C, et al.
Proceedings of the Combustion Institute, 33(1), 367-374 (2011)
Nadav Amdursky et al.
The journal of physical chemistry. A, 115(24), 6481-6487 (2011-05-19)
Time-resolved emission techniques were employed to study the nonradiative process of thioflavin-T (ThT) in 1-propanol, 1-butanol, and 1-pentanol as a function of the hydrostatic pressure. Elevated hydrostatic pressure increases the alcohol viscosity, which in turn strongly influences the nonradiative rate
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