379263
2-甲基-2-丁烯
technical grade, 90%
别名:
β-异戊烯, 戊烯
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关于此项目
线性分子式:
CH3CH=C(CH3)2
化学文摘社编号:
分子量:
70.13
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
208-156-3
Beilstein/REAXYS Number:
1361353
MDL number:
产品名称
2-甲基-2-丁烯, technical grade, 90%
InChI key
BKOOMYPCSUNDGP-UHFFFAOYSA-N
InChI
1S/C5H10/c1-4-5(2)3/h4H,1-3H3
SMILES string
C\C=C(\C)C
grade
technical grade
vapor density
2.4 (vs air)
vapor pressure
25.7 psi ( 55 °C)
7.95 psi ( 20 °C)
assay
90%
form
liquid
expl. lim.
8.7 %
refractive index
n20/D 1.385 (lit.)
bp
35-38 °C (lit.)
mp
−134 °C (lit.)
density
0.662 g/mL at 25 °C (lit.)
Quality Level
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Other Notes
推荐使用铜质软管接头 Z146811 或铜体微型气流阀 Z513539。
Application
2-Methyl-2-butene may be employed as precursor for peroxyacetyl nitrate for the calibration purposes.
General description
2-Methyl-2-butene (β-Isoamylene, Amylene) is a trisubstituted olefin. It acts as guest and forms stable solid host-guest complexes with self-assembled benzophenone bis-urea macrocycles. The effect of active chlorine formulations on photodecomposition of 2-methyl-2-butene has been studied. Its reaction with ozone in gas-phase has been reported to afford carbonym derivatives.
signalword
Danger
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Chronic 2 - Asp. Tox. 1 - Flam. Liq. 1 - Muta. 2 - STOT SE 3
target_organs
Central nervous system
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
-4.0 °F
flash_point_c
-20 °C
ppe
Eyeshields, Faceshields, Gloves
法规信息
新产品
此项目有
Gas-phase reaction of ozone with 2-methyl-2-butene: Dicarbonyl formation from Criegee biradicals.
Grosjean D.
Environmental Science & Technology, 24(9), 1428-1432 (1990)
Michael F Geer et al.
The Journal of organic chemistry, 78(11), 5568-5578 (2013-05-16)
This manuscript investigates how incorporation of benzophenone, a well-known triplet sensitizer, within a bis-urea macrocycle, which self-assembles into a columnar host, influences its photophysical properties and affects the reactivity of bound guest molecules. We further report the generation of a
Yunseok Im et al.
The Science of the total environment, 409(13), 2652-2661 (2011-04-29)
Active chlorine comprising hypochlorite (OCl⁻), hypochlorous acid (HOCl) and chlorine (Cl₂) is the active constituent in bleach formulations for a variety of industrial and consumer applications. However, the strong oxidative reactivity of active chlorine can cause adverse effects on both
Confined space-controlled hydroperoxidation of trisubstituted alkenes adsorbed on pentasil zeolites.
Yu-Zhe Chen et al.
The Journal of organic chemistry, 70(12), 4676-4681 (2005-06-04)
Photosensitized oxidation of trialkylalkenes 2-methyl-2-pentene (1), 1-methylcyclohexene (2), trans-3-methyl-2-pentene (3), cis-3-methyl-2-pentene (4), and 2-methyl-2-butene (5) included in the internal framework of Na-ZSM-5 zeolites was investigated. The zeolite samples having adsorbed the alkenes were suspended in isooctane, and the sensitizer, tetraphenylporphyrin
Charles K Westbrook et al.
The journal of physical chemistry. A, 119(28), 7462-7480 (2015-03-31)
Two experimental studies have been carried out on the oxidation of 2-methyl-2-butene, one measuring ignition delay times behind reflected shock waves in a stainless steel shock tube, and the other measuring fuel, intermediate, and product species mole fractions in a
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