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Merck
CN

372145

Sigma-Aldrich

三氯乙烯

anhydrous, contains 40 ppm diisopropylamine as stabilizer, ≥99%

别名:

TCE, 三氯代乙烯

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About This Item

线性分子式:
ClCH=CCl2
CAS号:
分子量:
131.39
Beilstein:
1736782
EC 号:
MDL编号:
UNSPSC代码:
12352101
PubChem化学物质编号:
NACRES:
NA.21
等级:
anhydrous
方案:
≥99%
沸点:
86.7 °C (lit.)
蒸汽压:
61 mmHg ( 20 °C)

等级

anhydrous

质量水平

蒸汽密度

4.5 (vs air)

蒸汽压

61 mmHg ( 20 °C)

方案

≥99%

表单

liquid

自燃温度

770 °F

包含

40 ppm diisopropylamine as stabilizer

杂质

<0.002% water
<0.005% water (100 mL pkg)

蒸发残留物

<0.0005%

折射率

n20/D 1.476 (lit.)

沸点

86.7 °C (lit.)

mp

−84.8 °C (lit.)

密度

1.463 g/mL at 25 °C (lit.)

SMILES字符串

Cl\C=C(\Cl)Cl

InChI

1S/C2HCl3/c3-1-2(4)5/h1H

InChI key

XSTXAVWGXDQKEL-UHFFFAOYSA-N

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一般描述

Trichloroethylene (TCE) is a chlorinated ethylene compound commonly used as a dry cleaning and degreasing solvent. Without stabilizers, TCE is unstable and degrades easily in the presence of moisture air, light and heat, it can be minimized by adding diisopropylamine as a stabilizer. Various methods have been reported for its synthesis. One of them is by chlorinating ethylene dichloride. Since TCE is one of the most common industrial solvent it has led it to be a major contaminant found in the ground water. It has adverse effect on human health due to its potential toxicity and carcinogenicity. Its toxicity and carcinogenicity has been studied.
Many methods have been proposed for the mineralization of TCE.

象形图

Health hazardExclamation mark

警示用语:

Danger

危险分类

Aquatic Chronic 3 - Carc. 1B - Eye Irrit. 2 - Muta. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

靶器官

Central nervous system

储存分类代码

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

WGK

WGK 3

闪点(°F)

closed cup - does not flash

闪点(°C)

closed cup - does not flash

个人防护装备

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

危险化学品

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分析证书(COA)

Lot/Batch Number

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E M Waters et al.
Journal of toxicology and environmental health, 2(3), 671-707 (1977-01-01)
Trichloroethylene (TCE) has been an industrial chemical of some importance for the past 50 years. First synthesized by Fischer in 1864, TCE has enjoyed considerable industrial usage as a degreaser and limited medical use as an inhalation anesthetic and analgesic.
Robert DM and Murphy B.
Chlorinated Solvents: A Forensic Evaluation, 125-131 null
A L Teel et al.
Water research, 35(4), 977-984 (2001-03-10)
Contaminant degradation, stoichiometry, and role of hydroxyl radicals (OH*) in four Fenton's systems were investigated using trichloroethylene (TCE) as a model contaminant. A standard Fenton's system, a modified soluble iron system with a pulse input of hydrogen peroxide, and two
Chlorinated Decreasing Solvents: Physical-Chemical Properties Affecting Aquifer Contamination and Remediation.
Jackson RE and Dwarakanath V.
Ground Water Monitoring & Remediation, 19(4), 102-110 (1999)
Anaerobic degradation of trichloroethylene in soil.
Kleopfer RD, et al.
Environmental Science & Technology, 19(3), 277-280 (1985)

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