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Merck
CN

35620

Supelco

2,6-二氯醌-4-氯亚胺

for spectrophotometric det. of vitamin B6, ≥99.0%

别名:

2,6-二氯苯醌氯亚胺, Gibb 试剂

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About This Item

经验公式(希尔记法):
C6H2Cl3NO
CAS号:
分子量:
210.45
Beilstein:
2364249
EC 号:
MDL编号:
UNSPSC代码:
41116105
PubChem化学物质编号:
NACRES:
NA.21

质量水平

方案

≥99.0% (AT)
≥99.0%

质量

for spectrophotometric det. of vitamin B6

技术

UV/Vis spectroscopy: suitable

mp

65-67 °C (lit.)
65-68 °C

应用

food and beverages
vitamins, nutraceuticals, and natural products

储存温度

2-8°C

SMILES字符串

Cl\N=C1\C=C(Cl)C(=O)C(Cl)=C1

InChI

1S/C6H2Cl3NO/c7-4-1-3(10-9)2-5(8)6(4)11/h1-2H

InChI key

YHUMTHWQGWPJOQ-UHFFFAOYSA-N

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一般描述

2,6-Dichloroquinone-4-chloroimide generally find application in being used as spot test and chromatographic spray reagents, mainly for phenols, though it can be used in detection of other types of compounds such as antioxidants, few primary and secondary amines, on silica gel chromatographic plates. Its decomposition rate is directly proportional to pressure.

应用

Gibb′s reagent was used in paper chromatography, in an experiment conducted to semi-quantitatively estimate tyramine and octopamine.

象形图

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警示用语:

Danger

危险声明

危险分类

Eye Irrit. 2 - Self-react. C - Skin Irrit. 2

储存分类代码

4.1A - Other explosive hazardous materials

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Colour reaction of phenols with the gibbs reagent. The reaction mechanism and decomposition and stabilisation of the reagent.
Svobodova D
Microchimica Acta, 67 (3-4), 251-264 (1977)
Occurrence and some properties of eledoisin in extracts of posterior salivary glands of Eledone.
Anastasi A and Erspamer V.
British Journal of Pharmacology and Chemotherapy, 19 (2), 326-336 (1962)
2, 6-Dichloroquinone 4-chloroimide as a reagent for amines and aromatic hydrocarbons on thin-layer chromatograms.
Hansbro RJ
Analytical Chemistry, 40 (14), 2138-2143 (1968)
Mohammad-Wadud Bhuiya et al.
Analytical biochemistry, 384(1), 151-158 (2008-10-18)
S-adenosyl-L-methionine (AdoMet)-dependent O-methyltransferases (OMTs) catalyze the transmethylation of a variety of phenolics in bacteria, plants, and humans. To rapidly characterize phenolic OMT activities, we adapted Gibbs' reagent, the dye originally used for detecting phenols, to develop a convenient assay method
Colorimetric determination of prenalterol hydrochloride in dosage forms.
F A Aly et al.
Journal of pharmaceutical and biomedical analysis, 12(7), 955-958 (1994-07-01)

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