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Merck
CN

34862-M

Sigma-Aldrich

2,2,4-三甲基戊烷

suitable for HPLC, ≥99%

别名:

异辛烷

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About This Item

线性分子式:
(CH3)2CHCH2C(CH3)3
CAS号:
分子量:
114.23
Beilstein:
1696876
EC 号:
MDL编号:
UNSPSC代码:
12190000
PubChem化学物质编号:
NACRES:
NA.21
方案:
≥99%
技术:
HPLC: suitable
沸点:
98-99 °C (lit.)
蒸汽压:
41 mmHg ( 21 °C)

蒸汽密度

3.9 (vs air)

蒸汽压

41 mmHg ( 21 °C)

方案

≥99%

表单

liquid

自燃温度

745 °F

expl. lim.

6 %

技术

HPLC: suitable

杂质

≤0.0005% non-volatile matter
≤0.001% free acid (as CH3COOH)
≤0.01% water (Karl Fischer)

透射比

210 nm, ≥20%
235 nm, ≥80%
270 nm, ≥98%

折射率

n20/D 1.391 (lit.)

沸点

98-99 °C (lit.)

mp

−107 °C (lit.)

密度

0.692 g/mL at 25 °C (lit.)

SMILES字符串

CC(C)CC(C)(C)C

InChI

1S/C8H18/c1-7(2)6-8(3,4)5/h7H,6H2,1-5H3

InChI key

NHTMVDHEPJAVLT-UHFFFAOYSA-N

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一般描述

2,2,4-Trimethylpentane (TMP, Isooctane) is a saturated, branched hydrocarbon. It has been reported to be nephrotoxic to male rats. Density and viscosity of TMP at various temperatures (198K - 348K) and pressures (100MPa) has been evaluated. It has been indentified as nephrotoxicity inducing component in unleaded gasoline.

应用

2,2,4-Trimethylpentane (TMP, Isooctane) has been used for the isolation of mercury species during the HPLC cold vapor atomic fluorescence spectrometric (HPLC-CVAFS) quantification of MeHg in various biological samples. It may be used to evaluate various physical properties (densities, viscosities, refractive indexes and surface tensions) of the binary mixtures of TMP and cyclohexane.

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警示用语:

Danger

危险分类

Aquatic Acute 1 - Aquatic Chronic 1 - Asp. Tox. 1 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Central nervous system

储存分类代码

3 - Flammable liquids

WGK

WGK 2

闪点(°F)

10.4 °F - closed cup

闪点(°C)

-12.00 °C - closed cup

法规信息

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分析证书(COA)

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B G Short et al.
Toxicologic pathology, 14(2), 194-203 (1986-01-01)
Unleaded gasoline causes acute and chronic nephrotoxicity and renal tumors in male rats, but not female rats or mice of either sex. An active nephrotoxic component of unleaded gasoline has been identified as 2,2,4-trimethylpentane (TMP). The first objective of this
E A Lock et al.
Toxicology and applied pharmacology, 91(2), 182-192 (1987-11-01)
Trimethylpentane (TMP) produces nephrotoxicity in male but not in female rats. The toxicity is characterized by an increase in protein droplets in proximal convoluted tubular cells and an increase in the renal concentration of the male-rat-specific protein alpha 2u-globulin. Subcellular
Christoph-Cornelius Brombach et al.
Analytical and bioanalytical chemistry, 407(3), 973-981 (2014-10-17)
Mercury (Hg) is a global pollutant which occurs in different species, with methylmercury (MeHg) being the critical compound due to its neurotoxicity and bioaccumulation through the food chain. Methods for trace speciation of MeHg are therefore needed for a vast

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