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Merck
CN

33681

Supelco

BDE No 100 溶液

50 μg/mL in isooctane, analytical standard

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别名:
2,2′,4,4′,6-五溴二苯醚 溶液, 2,2′,4,4′,6-PentaBDE, PBDE 100
经验公式(希尔记法):
C12H5Br5O
分子量:
564.69
EC 号:
MDL编号:
UNSPSC代码:
41116107
PubChem化学物质编号:
NACRES:
NA.24

等级

analytical standard

质量水平

保质期

limited shelf life, expiry date on the label

浓度

50 μg/mL in isooctane

技术

HPLC: suitable
gas chromatography (GC): suitable

应用

environmental

格式

single component solution

储存温度

2-8°C

SMILES字符串

Brc1ccc(Oc2c(Br)cc(Br)cc2Br)c(Br)c1

InChI

1S/C12H5Br5O/c13-6-1-2-11(8(15)3-6)18-12-9(16)4-7(14)5-10(12)17/h1-5H

InChI key

NSKIRYMHNFTRLR-UHFFFAOYSA-N

一般描述

BDE No 100 is a low acute toxicity pollutant, belonging to the class of polybrominated diphenyl ethers. It can be commercially used as a flame retardant additive in building materials, textiles, plastics, and electronic equipments.

应用

BDE No 100 may be used as an analytical reference standard for the determination of the analyte in:
  • House dust samples using isotope dilution method combined with liquid chromatography coupled to negative ionization atmospheric pressure photoionization tandem mass spectrometry (LC-NI-APPI-MS/MS).
  • Adipose tissue samples using gas chromatography coupled to ion-trap mass spectrometry (GC-IT-MS/MS).

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

其他说明

The customer needs to make sure that the standard is homogeneous, this can be achieved by shaking, vortexing , or sonicating the ampoule before opening the ampoule. Care should be taken when opening the ampoule to avoid any injuries from the broken glass.
The standard should be transferred to a clean and appropriate vial or flask using clean pipettes or micro pipettes. The vial should be immediately capped to avoid any loss or evaporation of the solvent.
After opening the ampoule, the standard should not be stored or kept in the ampoule. To preserve the integrity of the product, the standard should be transferred to an appropriate vial that must be capped and stored according to the recommendation on the Certificate of Analysis.

警示用语:

Danger

危险分类

Aquatic Acute 1 - Aquatic Chronic 1 - Asp. Tox. 1 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Central nervous system

WGK

WGK 2

闪点(°F)

10.4 °F

闪点(°C)

-12 °C

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

危险化学品

分析证书(COA)

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Youssef Oulhote et al.
Environment international, 119, 79-88 (2018-06-26)
Prenatal exposure to polybrominated diphenyl ethers (PBDEs) has been associated with cognitive deficits and behavioral problems in children. To date, no study has examined this exposure in association with neurobehavioral development in infants younger than 12 months assessed with observational tasks.
Isotope dilution method for determination of polybrominated diphenyl ethers using liquid chromatography coupled to negative ionization atmospheric pressure photoionization tandem mass spectrometry: validation and application to house dust.
Abdallah E-A M, et al.
Analytical Chemistry, 81(17), 7460-7469 (2009)
Development of a gas chromatography/ion trap mass spectrometry based method for the quantification of polybrominated diphenyl ethers and polychlorinated biphenyls in adipose tissue.
Naert C, et al.
Rapid Communications in Mass Spectrometry, 18(19), 2317-2332 (2004)
Luca Maria Chiesa et al.
Food additives & contaminants. Part A, Chemistry, analysis, control, exposure & risk assessment, 35(7), 1340-1355 (2018-03-14)
Demand for honey is increasing, especially if it is organic and if its nutritional properties are linked to untreated environments in order to guarantee quality for health. Sources of contamination of honey can be divided into environmental and apicultural. Therefore

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