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蒸汽压
0.4 mmHg ( 20 °C)
质量水平
方案
≥99%
表单
liquid
自燃温度
977 °F
纯化方式
redistillation
expl. lim.
15.7 %
杂质
≤19 ppm Triazine
<0.005% water
折射率
n20/D 1.495 (lit.)
沸点
198 °C (lit.)
mp
−6 °C (lit.)
密度
1.03 g/mL at 25 °C (lit.)
1.034-1.036 g/mL
SMILES字符串
Cn1ccnc1
InChI
1S/C4H6N2/c1-6-3-2-5-4-6/h2-4H,1H3
InChI key
MCTWTZJPVLRJOU-UHFFFAOYSA-N
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一般描述
1-甲基咪唑是一种 N-给电子配体,通常用于配位配合物的制备。
应用
1-甲基咪唑可用作如下物质合成的起始原料:
- 1-(2-羟丙基)-3-甲基咪唑鎓盐(用作离子液体)
- 1,3-二甲基咪唑基-2-亚基硼烷(一种稳定且易于处理的 N-杂环卡宾硼烷)
- 它可以作为醛糖醛酸乙二醇酯合成中的催化剂和溶剂。
包装
查看可回收的容器产品。
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说明
价格
警示用语:
Danger
危险分类
Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Eye Dam. 1 - Repr. 2 - Skin Corr. 1B
储存分类代码
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGK
WGK 2
闪点(°F)
197.6 °F - closed cup
闪点(°C)
92 °C - closed cup
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Nickel (II)-, cobalt (II)-, copper (II)-, and zinc (II)-phthalate and 1-methylimidazole coordination compounds: synthesis, crystal structures and magnetic properties.
Inorgorganica Chimica Acta, 357(12), 3419-3429 (2004)
1,3-Dimethylimidazoyl-2-ylidene borane
Organic Syntheses, 92, 342-342 (2015)
New ionic liquids containing an appended hydroxyl functionality from the atom-efficient, one-pot reaction of 1-methylimidazole and acid with propylene oxide.
Green Chemistry, 5(6), 731-736 (2003)
The use of 1-methylimidazole as a solvent and catalyst for the preparation of aldononitrile acetates of aldoses.
Carbohydrate Research, 90(1), 127-130 (1981)
Bioorganic & medicinal chemistry, 20(8), 2656-2660 (2012-03-13)
Epigenetic modifications that govern the gene expression are often overlooked with the design of artificial genetic switches. N-Methylpyrrole-N-methylimidazole (PI) hairpin polyamides are programmable small DNA binding molecules that have been studied in the context of gene regulation. Recently, we synthesized
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