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Merck
CN

33603

十五氟辛酸 溶液

100 μg/mL in methanol, analytical standard

别名:

PFOA, 全氟辛酸 溶液, 十五氟八碳酸 溶液

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关于此项目

线性分子式:
CF3(CF2)6COOH
化学文摘社编号:
335-67-1
分子量:
414.07
NACRES:
NA.24
PubChem Substance ID:
329754596
UNSPSC Code:
85151701
EC Number:
200-659-6
MDL number:
MFCD00004174

主要文件

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产品名称

十五氟辛酸 溶液, 100 μg/mL in methanol, analytical standard

application(s)

PFAS testing
cleaning products
cosmetics
environmental
food and beverages
personal care

format

single component solution

storage temp.

2-8°C

InChI key

SNGREZUHAYWORS-UHFFFAOYSA-N

InChI

1S/C8HF15O2/c9-2(10,1(24)25)3(11,12)4(13,14)5(15,16)6(17,18)7(19,20)8(21,22)23/h(H,24,25)

SMILES string

OC(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F

grade

analytical standard

agency

suitable for ASTM® 7968
suitable for ASTM® 7979
suitable for DIN 38407-42
suitable for EPA 1633
suitable for EPA 533
suitable for EPA 537.1
suitable for EPA 8327
suitable for EPA ACB B21-02
suitable for EPA ACB B23-05b
suitable for EPA OTM-45
suitable for ISO 21675 2019
suitable for ISO 25101

reg. compliance

suitable for FDA C-010.02

shelf life

limited shelf life, expiry date on the label

concentration

100 μg/mL in methanol

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

Quality Level

100

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相关类别

Application

Pentadecafluorooctanoic acid solution may be used as an ion-pairing agent in the determination of chlorhexidine in body fluids and pharmaceutical preparations, using high performance liquid chromatography(HPLC). It may also be used as an additive in the extraction of potassium ion in aqueous solution using supercritical carbon dioxide.
Pentadecafluorooctanoic acid solution may be used as an ion-pairing reagent in the development of a chromatographic method for the separation and determination of underivatized proteinic amino acids using liquid chromatography with evaporative light scattering detection (LC-ELSD) and atmospheric pressure ionization-mass spectrometry (LC-API-MS), respectively.
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

General description

This compound is listed in the SVHC (Substances of very high concern) candidate list of ECHA (European Chemicals Agency)

Other Notes

The customer needs to make sure that the standard is homogeneous, this can be achieved by shaking, vortexing , or sonicating the ampoule before opening the ampoule. Care should be taken when opening the ampoule to avoid any injuries from the broken glass.
The standard should be transferred to a clean and appropriate vial or flask using clean pipettes or micro pipettes. The vial should be immediately capped to avoid any loss or evaporation of the solvent.
After opening the ampoule, the standard should not be stored or kept in the ampoule. To preserve the integrity of the product, the standard should be transferred to an appropriate vial that must be capped and stored according to the recommendation on the Certificate of Analysis.

Legal Information

ASTM is a registered trademark of American Society for Testing and Materials

signalword

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Flam. Liq. 2 - STOT SE 1

target_organs

Eyes,Central nervous system

存储类别

3 - Flammable liquids

wgk

WGK 2

flash_point_f

51.8 °F - closed cup

flash_point_c

11 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

危险化学品
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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
BCCN8132
BCCN0710
BCCM8418
BCCM3546
BCCL3743

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High-performance liquid chromatographic method for the determination of chlorhexidine
Huston.EC, et al.
Journal of Chromatography A, 237, 457-464 (1982)
Determination of 20 underivatized proteinic amino acids by ion-pairing chromatography and pneumatically assisted electrospray mass spectrometry.
Chaimbault P, et al.
Journal of Chromatography A, 855(1), 191-202 (1999)
Perfluorocarboxylic acid counter ion enhanced extraction of aqueous alkali metal ions with supercritical carbon dioxide
Mochizuki S, et al.
Analyst, 124, 1507-1511 (1999)
Mei-Huei Chen et al.
Epidemiology (Cambridge, Mass.), 24(6), 800-808 (2013-09-17)
Epidemiologic data regarding the potential neurotoxicity of perfluorinated compounds (PFCs) are inconclusive. We investigated the associations between in utero exposure to perfluorooctanoic acid (PFOA) and perfluorooctyl sulfonate (PFOS) and early childhood neurodevelopment. We recruited 239 mother-infant pairs in northern Taiwan
A K Rosenmai et al.
Toxicology and applied pharmacology, 266(1), 132-142 (2012-11-13)
Polyfluoroalkyl phosphate surfactants (PAPS) are widely used in food contact materials (FCMs) of paper and board and have recently been detected in 57% of investigated materials. Human exposure occurs as PAPS have been measured in blood; however knowledge is lacking
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