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33510

Sigma-Aldrich

1,10-菲咯啉 一水合物

redox indicator, ACS reagent, puriss. p.a., ≥99.5% (calc. to the dried substance)

别名:

邻菲咯啉 一水合物

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About This Item

经验公式（希尔记法）:
C12H8N2 · H2O
CAS号:
5144-89-8
分子量:
198.22
Beilstein:
4008096
EC 号:
200-629-2
MDL编号:
MFCD00149973
UNSPSC代码:
12352100
PubChem化学物质编号:
57648856
NACRES:
NA.21

产品名称

1,10-菲咯啉 一水合物, ACS reagent, puriss. p.a., ≥99.5% (calc. to the dried substance), for redox titration

等级

ACS reagent
puriss. p.a.

质量水平

200

方案

≥99.5% (calc. to the dried substance)
8.5-9.5% water basis

技术

titration: suitable

杂质

8.5-9.5% water

灼烧残渣

≤0.05% (as SO4)

mp

100-104 °C (lit.)
97-102 °C

适用性

passes test for iron detection
passes test for redox indicator

SMILES字符串

O.c1cnc2c(c1)ccc3cccnc23

InChI

1S/C12H8N2.H2O/c1-3-9-5-6-10-4-2-8-14-12(10)11(9)13-7-1;/h1-8H;1H2

InChI key

PPQJCISYYXZCAE-UHFFFAOYSA-N

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一般描述

1,10-菲咯啉一水合物是 o -菲咯啉的水合形式。

应用

1,10-菲咯啉一水合物（苯酚的）可用于矿物样品中 Fe 3 + 和总铁的光化学定量。可用作制备 5-硝基-1,10-菲咯啉的起始试剂。
当与铜络合时，具有核酸酶活性，用于研究 DNA-蛋白质相互作用。

生化/生理作用

金属蛋白酶抑制剂;可与铁、锌和其他二价金属形成螯合物。有效浓度 1-10mM。

象形图

Skull and crossbonesEnvironment
GHS06,GHS09

警示用语：

Danger

危险声明

H301,H410

危险分类

Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1

储存分类代码

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

从最新的版本中选择一种：

分析证书(COA)

Lot/Batch Number
BCCM5250
BCCL5564
BCCL8757
BCCG1840
BCCC0594

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The quantitative assay of minerals for Fe2+ and Fe3+ using 1, 10-phenanthroline: II. A photochemical method.
Stucki JW.
Soil Science Society of America Journal. Soil Science Society of America, 45(3), 638-641 (1981)
Kyle R Simonetta et al.
Nature communications, 10(1), 1402-1402 (2019-03-31)
Protein-protein interactions (PPIs) governing the recognition of substrates by E3 ubiquitin ligases are critical to cellular function. There is significant therapeutic potential in the development of small molecules that modulate these interactions; however, rational design of small molecule enhancers of
A luminescent tris (2-thenoyltrifluoroacetonato) europium (III) complex covalently linked to a 1, 10-phenanthroline-functionalised sol-gel glass.
Binnemans K, et al.
Journal of Materials Chemistry, 14(2), 191-195 (2004)
Unmesh Jadhav et al.
Molecular cell, 78(1), 141-151 (2020-02-07)
Polycomb repressive complex 2 (PRC2) places H3K27me3 at developmental genes and is causally implicated in keeping bivalent genes silent. It is unclear if that silence requires minimum H3K27me3 levels and how the mark transmits faithfully across mammalian somatic cell generations.
Doo Sin Jo et al.
Autophagy, 16(11), 1989-2003 (2020-01-23)
Quality control of peroxisomes is essential for cellular homeostasis. However, the mechanism underlying pexophagy is largely unknown. In this study, we identified HSPA9 as a novel pexophagy regulator. Downregulation of HSPA9 increased macroautophagy/autophagy but decreased the number of peroxisomes in
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