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Merck
CN

33490

HMDI

analytical standard

别名:

4,4′-二异氰酸酯二环己基甲烷, 1,1′-亚甲二(4-异氰酸基环己烷), 4,4′-HMDI, 二环己基甲烷-4,4′-二异氰酸酯

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关于此项目

线性分子式:
CH2(C6H10NCO)2
化学文摘社编号:
5124-30-1
分子量:
262.35
UNSPSC Code:
41116107
NACRES:
NA.24
PubChem Substance ID:
329754560
EC Number:
225-863-2
Beilstein/REAXYS Number:
2217800
MDL number:
MFCD00015405

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产品名称

HMDI, analytical standard

InChI key

KORSJDCBLAPZEQ-UHFFFAOYSA-N

InChI

1S/C15H22N2O2/c18-10-16-14-5-1-12(2-6-14)9-13-3-7-15(8-4-13)17-11-19/h12-15H,1-9H2

SMILES string

O=C=NC1CCC(CC1)CC2CCC(CC2)N=C=O

grade

analytical standard

quality

mixture of isomers

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

environmental

format

neat

Quality Level

100

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Application

有关合适仪器技术的更多信息，请参考产品分析证书。如需进一步支持，请联系技术服务部门。

General description

该物质被列入欧盟法规10/2011中关于拟与食品接触的塑料的积极清单。

pictograms

Skull and crossbonesHealth hazard
GHS06,GHS08

signalword

Danger

Hazard Classifications

Acute Tox. 2 Inhalation - Eye Irrit. 2 - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

target_organs

Respiratory system

存储类别

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 1

flash_point_f

235.4 °F - closed cup

flash_point_c

113 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
BCCN0186
BCCM1391
BCCL3955
BCCL1543
BCCK8987

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Extensive skin sensitization with minimal antibody production in guinea pigs as a result of exposure to dicyclohexylmethane-4,4'-diisocyanate.
M H Karol et al.
Toxicology and applied pharmacology, 65(2), 291-301 (1982-09-15)
T-W Chuang et al.
Journal of biomedical materials research. Part A, 85(3), 722-730 (2007-09-28)
Poor compatibility between blood and metallic coronary artery stents is one reason for arterial restenosis. Immobilization of anticoagulant agents on the stent's surface is feasible for improving compatibility. We examined possible surface-coupling agents for anticoagulant agent immobilization. Hexamethylene diisocyanate (HMDI)
L H Chan-Chan et al.
Acta biomaterialia, 6(6), 2035-2044 (2009-12-17)
Biodegradable segmented polyurethanes (BSPUs) were prepared with poly(caprolactone) as a soft segment, 4,4'-methylene bis (cyclohexyl isocyanate) and either butanediol (BSPU1) or dithioerythritol (BSPU2) as a chain extender. BSPU samples were characterized in terms of their physicochemical properties and their hemocompatibility.
Tzu-Wen Chuang et al.
Journal of biomedical materials research. Part A, 86(3), 648-661 (2007-11-21)
Poor compatibility between blood and metallic coronary artery stents is one reason for arterial restenosis; however, the immobilization of anticoagulant agents on the surface of the stent is a feasible method of improving stent compatibility. Heparin, a well-known anticoagulant, has
I R White et al.
Contact dermatitis, 9(4), 300-303 (1983-07-01)
Organic di-isocyanates are used widely in industry. The concomitant respiratory complications are well-known. Cutaneous problems precipitated by skin contact with these chemicals are less well recognised. Allergic contact dermatitis caused by exposure to di-cyclohexylmethane 4,4'-di-isocyanate has been demonstrated in a
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