33380
4-甲基-邻-苯二胺
purum, ≥98.0% (NT)
别名:
3,4-甲苯二胺
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关于此项目
线性分子式:
CH3C6H3(NH2)2
化学文摘社编号:
分子量:
122.17
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
207-826-2
Beilstein/REAXYS Number:
507965
MDL number:
产品名称
4-甲基-邻-苯二胺, purum, ≥98.0% (NT)
InChI key
DGRGLKZMKWPMOH-UHFFFAOYSA-N
InChI
1S/C7H10N2/c1-5-2-3-6(8)7(9)4-5/h2-4H,8-9H2,1H3
SMILES string
Cc1ccc(N)c(N)c1
grade
purum
assay
≥98.0% (NT)
bp
155-156 °C/18 mmHg (lit.)
mp
87-89 °C (lit.)
87-89 °C
application(s)
agriculture
environmental
Quality Level
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Application
4-甲基邻苯二胺在硒（IV）的分光光度测定中用作显色试剂。它用于通过与脱氢乙酸和水杨醛缩合合成不对称四齿席夫碱。
General description
4-甲基-邻苯二胺是邻苯二胺的 4-取代衍生物。在酸性溶液中与亚硒酸反应生成苯并硒二唑。
signalword
Warning
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 1
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Synthesis, characterization and thermal study of some transition metal complexes of an asymmetrical tetradentate Schiff base ligand.
Munde AS, et al.
J. Serb. Chem. Soc., 75(3), 349-359 (2010)
Spectrophotometric determination of selenium (IV) with 4-methyl-o-phenylenediamine based on piazselenol formation.
Kartal S, et al.
Journal of Analytical Chemistry, 65(12), 1221-1227 (2010)
Some 4-substituted< i> o</i>-phenylenediamines as reagents for selenium.
Tanaka M and Kawashima T.
Talanta, 12(3), 211-219 (1965)
P J Becci et al.
Toxicology and applied pharmacology, 71(3), 323-329 (1983-12-01)
o-Toluenediamine in corn oil was administered po to Sprague-Dawley rats at dosages of 10, 30, 100, or 300 mg/kg body wt/day during Days 6 through 15 of gestation. All animals were killed on Day 20 of gestation. A similar study
Christina L Burnett et al.
International journal of toxicology, 29(3 Suppl), 61S-83S (2010-05-22)
Toluene-2,5-diamine, toluene-2,5-diamine sulfate, and toluene-3,4-diamine are diaminotoluenes used as colorants in permanent hair dyes and tints. Toluene-2,5-diamine is used in 79 products at concentrations up to 3%; toluene-2,5-diamine sulfate is used in 168 products at concentrations up to 4%. Toluene-3,4-diamine
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