33325
邻苯二甲酸氢钾
puriss. p.a., buffer substance, ≥99.5%
别名:
KHP, 苯二甲酸氢钾, 邻苯二甲酸 单钾盐, 酞酸氢钾
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线性分子式:
HOOCC6H4COOK
化学文摘社编号:
分子量:
204.22
UNSPSC Code:
12352100
NACRES:
NA.21
PubChem Substance ID:
EC Number:
212-889-4
Beilstein/REAXYS Number:
3637128
MDL number:
InChI key
IWZKICVEHNUQTL-UHFFFAOYSA-M
InChI
1S/C8H6O4.K/c9-7(10)5-3-1-2-4-6(5)8(11)12;/h1-4H,(H,9,10)(H,11,12);/q;+1/p-1
SMILES string
[K+].OC(=O)c1ccccc1C([O-])=O
grade
puriss. p.a.
assay
≥99.5%
form
solid
loss
≤0.2% loss on drying, 105 °C
pH
4
mp
295-300 °C (dec.) (lit.)
anion traces
chloride (Cl-): ≤10 mg/kg, sulfate (SO42-): ≤50 mg/kg
cation traces
Cd: ≤5 mg/kg, Co: ≤5 mg/kg, Cu: ≤5 mg/kg, Fe: ≤5 mg/kg, Na: ≤100 mg/kg, Ni: ≤5 mg/kg, Pb: ≤5 mg/kg, Zn: ≤5 mg/kg
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General description
Potassium phthalate monobasic is the monopotassium salt of phthalic acid. It has been proposed as a certified reference material (CRM) under ISO/IEC 17025 and ISO Guide 34 accreditation. Its spectral shift, multiplicity, solubility and relaxation times in different solvents have been reported.
Application
Potassium phthalate monobasic may be used as a buffer to maintain pH = 2.39 and 4.52, during the dispersive ionic liquid-liquid microextraction coupled with liquid chromatography and UV detection of drug (benznidazole and nifurtimox) levels in human plasma. It has been used as internal standard certified reference material (CRM) for the high performance (HP)-quantitative NMR spectroscopic (qNMR) determination of various organic compounds.
flash_point_f
387.1 °F - Pensky-Martens closed cup
flash_point_c
197.3 °C - Pensky-Martens closed cup
ppe
Eyeshields, Gloves, type N95 (US)
存储类别
11 - Combustible Solids
wgk
WGK 1
法规信息
新产品
此项目有
J M Padró et al.
Talanta, 107, 95-102 (2013-04-20)
Dispersive ionic liquid-liquid microextraction combined with liquid chromatography and UV detection was used for the determination of two antichagasic drugs in human plasma: nifurtimox and benznidazole. The effects of experimental parameters on extraction efficiency-the type and volume of ionic liquid
Maria Cristina Fossi et al.
Marine pollution bulletin, 64(11), 2374-2379 (2012-09-12)
Baleen whales are potentially exposed to micro-litter ingestion as a result of their filter-feeding activity. However, the impacts of microplastics on baleen whales are largely unknown. In this case study of the Mediterranean fin whale (Balaenoptera physalus), we explore the
Hanne Frederiksen et al.
Environmental science & technology, 47(2), 958-967 (2012-12-14)
Urinary phthalate excretion is used as marker of phthalate exposure in epidemiological studies. Here we examine the reliability of urinary phthalate levels in exposure classification by comparing the inter- and intrasubject variation of urinary phthalate metabolite levels. Thirty-three young healthy
Juanjuan Feng et al.
Journal of chromatography. A, 1268, 16-21 (2012-11-07)
Because of the occurrence of ion exchange between high-ionic-strength solution and anions of polymeric ionic liquids (PILs), PILs based solid-phase microextraction (SPME) fibers were rarely used in direct immersion mode to high-salt-added samples. In this work, a novel double-confined PIL
Michael Weber et al.
Journal of pharmaceutical and biomedical analysis, 93, 102-110 (2013-11-05)
Quantitative NMR spectroscopy (qNMR) is gaining interest across both analytical and industrial research applications and has become an essential tool for the content assignment and quantitative determination of impurities. The key benefits of using qNMR as measurement method for the
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