32328
倒千里光裂碱
analytical standard
别名:
(1R,7aR)-2,3,5,7a-Tetrahydro-1-hydroxy-1H-pyrrolizine-7-methanol
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关于此项目
经验公式（希尔记法）:
C8H13NO2
化学文摘社编号:
分子量:
155.19
NACRES:
NA.24
PubChem Substance ID:
UNSPSC Code:
85151701
MDL number:
InChI key
HJSJELVDQOXCHO-HTQZYQBOSA-N
SMILES string
[H][C@@]1([C@H](O)CC2)N2CC=C1CO
InChI
1S/C8H13NO2/c10-5-6-1-3-9-4-2-7(11)8(6)9/h1,7-8,10-11H,2-5H2/t7-,8-/m1/s1
grade
analytical standard
shelf life
limited shelf life, expiry date on the label
storage condition
under inert gas
technique(s)
HPLC: suitable, gas chromatography (GC): suitable
format
neat
storage temp.
2-8°C
Quality Level
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Application
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 2 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral
存储类别
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Fang Zhang et al.
Analytica chimica acta, 605(1), 94-101 (2007-11-21)
Pyrrolizidine alkaloids (PAs) are alkaloids which typically contain a necine (7-hydroxy-1-hydroxymethyl-6,7-dihydro-5H-pyrrolizidine) base unit, and they can be found in one third of the higher plants around the world. They are hepatotoxic, mutagenic and carcinogenic and pose a threat to human
Steven M Colegate et al.
Phytochemical analysis : PCA, 24(3), 201-212 (2012-10-17)
A livestock poisoning outbreak near Kingman, Arizona, USA, potentially linked to dehydropyrrolizidine alkaloids, prompted an evaluation of some local plants for the presence of these hepatotoxic alkaloids. To qualitatively and quantitatively examine two species of Cryptantha, a Boraginaceous genus previously
L H Zalkow et al.
Journal of medicinal chemistry, 31(8), 1520-1526 (1988-08-01)
The C-9 and C-7 monoesters and C-7, C-9 diesters of heliotridine with (S)-(+) and (R)-(-)-2-hydroxy-2-phenylbutyric acid were prepared, converted into their N-oxides, and compared with the corresponding C-9 monoesters of retronecine in the in vivo P388 lymphocytic leukemia screen. Relative
John A Edgar et al.
Journal of chemical ecology, 33(12), 2266-2280 (2007-11-22)
Many pyrrolizidine alkaloid (PA)-adapted insects convert PAs sequestered from their larval host plants into "insect-PAs" in which the acid components of the alkaloids are replaced by small, branched aliphatic 2-hydroxy acids of insect origin. It has been proposed that insect-PAs
Reactions of iminium ions with Michael acceptors through a Morita-Baylis-Hillman-type reaction: enantiocontrol and applications in synthesis.
Eddie L Myers et al.
Angewandte Chemie (International ed. in English), 46(11), 1893-1896 (2007-02-06)
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