31653
锌
ACS reagent grade, ≥99.9%, granular, puriss. p.a., reag. ISO, reag. Ph. Eur.
别名:
Zn
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关于此项目
经验公式（希尔记法）:
Zn
化学文摘社编号:
分子量:
65.39
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
11101719
EC Number:
231-175-3
MDL number:
产品名称
锌, puriss. p.a., ACS reagent, reag. ISO, reag. Ph. Eur., ≥99.9%, granular
InChI key
HCHKCACWOHOZIP-UHFFFAOYSA-N
InChI
1S/Zn
SMILES string
[Zn]
grade
ACS reagent
puriss. p.a.
agency
USP/NF
reag. ISO
reag. Ph. Eur.
vapor pressure
1 mmHg ( 487 °C)
assay
≥99.9%
form
granular
reaction suitability
core: zinc
reagent type: catalyst
resistivity
5.8 μΩ-cm, 20°C
bp
907 °C (lit.)
mp
420 °C (lit.)
density
7.133 g/mL at 25 °C (lit.)
cation traces
As: ≤0.1 mg/kg
Cd: ≤5 mg/kg
Cu: ≤10 mg/kg
Fe: ≤20 mg/kg
Pb: ≤50 mg/kg
Sn: ≤10 mg/kg
Quality Level
Application
锌可用于制备有机锌试剂、Reformatsky 试剂 和 Simmons-Smith 试剂。
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Use of activation methods for organozinc reagents.
Erdik E
Tetrahedron, 43(10), 2203-2212 (1987)
A scalable zinc activation procedure using dibal-h in a reformatsky reaction.
Girgis M J
Organic Process Research & Development, 13(6), 1094-1099 (2009)
A Convenient Procedure for the Preparation of Reactive Zinc for the Reformatsky Reaction.
Bouhel E
Synthetic Communications, 21(1), 133-136 (1991)
Highly efficient, general procedure for the preparation of alkylzinc reagents from unactivated alkyl bromides and chlorides.
Huo S
Organic Letters, 5(4), 423-425 (2003)
Cyclopropanation of Electron-deficient Olefins with Dibromomethane by Ni (0) Complexes and Zinc.
Kanai H
Bulletin of the Chemical Society of Japan, 56(4), 1025-1029 (1983)
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