31598
4-氨基联苯
analytical standard
别名:
4-氨基联苯, 4-联苯胺, 4-苯基苯胺, NSC 7660, 对氨基苯胺, 联苯-4-基胺, 联苯基胺
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线性分子式:
C6H5C6H4NH2
化学文摘社编号:
分子量:
169.22
UNSPSC Code:
41116107
NACRES:
NA.24
PubChem Substance ID:
EC Number:
202-177-1
Beilstein/REAXYS Number:
386533
MDL number:
产品名称
4-氨基联苯, analytical standard
InChI key
DMVOXQPQNTYEKQ-UHFFFAOYSA-N
InChI
1S/C12H11N/c13-12-8-6-11(7-9-12)10-4-2-1-3-5-10/h1-9H,13H2
SMILES string
Nc1ccc(cc1)-c2ccccc2
grade
analytical standard
autoignition temp.
842 °F
shelf life
limited shelf life, expiry date on the label
technique(s)
HPLC: suitable
gas chromatography (GC): suitable
bp
191 °C/15 mmHg (lit.)
mp
52-54 °C (lit.)
application(s)
cleaning products
cosmetics
environmental
food and beverages
personal care
format
neat
Quality Level
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Application
4-Aminobiphenyl has been used as an analytical reference standard for the analysis of 4-aminobiphenyl in food packaging materials by liquid chromatography-full scan-high resolution mass spectrometry (LC-HRMS).
It may be used as an analytical reference standard for the determination of 4-aminobiphenyl in:
It may be used as an analytical reference standard for the determination of 4-aminobiphenyl in:
- Particulate phase mainstream cigarette smoke samples by solid-phase extraction (SPE) and gas chromatography coupled to MS equipped with selected ion monitoring (SIM) mode of detection as well as simultaneous distillation and extraction (SDE) and GC-MS with SIM detection.
- Environmental water samples by hollow fiber-liquid phase microextraction (HF-LPME) and microemulsion electrokinetic chromatography (MEEKC).
- Indoor and outdoor air samples by GC-MS.
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
General description
4-Aminobiphenyl is classified under the aromatic amine group of compounds.
This compound is listed in the SVHC (Substances of very high concern) candidate list of ECHA (European Chemicals Agency)
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Carc. 1A
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
法规信息
危险化学品
此项目有
Simultaneous determination of aliphatic and aromatic amines in indoor and outdoor air samples by gas chromatography-mass spectrometry.
Akyuz M.
Talanta, 71(1), 486-492 (2007)
Analysis of polycyclic aromatic hydrocarbons, phenols and aromatic amines in particulate phase cigarette smoke using simultaneous distillation and extraction as a sole sample clean-up step.
Forehand JB, et al.
Journal of Chromatography A, 898(1), 111-124 (2000)
Samuel M Cohen et al.
Critical reviews in toxicology, 36(10), 803-819 (2006-11-23)
The IPCS Human Relevance Framework was evaluated for a DNA-reactive (genotoxic) carcinogen, 4-aminobiphenyl, based on a wealth of data in animals and humans. The mode of action involves metabolic activation by N-hydroxylation, followed by N-esterification leading to the formation of
Moinuddin et al.
Environmental toxicology, 29(5), 568-576 (2012-05-23)
4-Aminobiphenyl (4-ABP), an aromatic amine is a major environmental carcinogen found mainly in cigarette smoke. It has been vastly implicated in mutagenesis and cancer development. In this study, commercially available human placental DNA was exposed to 4-ABP (1.3 mM) in
Determination of aromatic amines in environmental water sample by hollow fiber-liquid phase microextraction and microemulsion electrokinetic chromatography.
Lin Z, et al.
Journal of Chromatography A, 1217(26), 4507-4510 (2010)
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