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安全信息

31107-M

Sigma-Aldrich

氯化铵

puriss. p.a., ACS reagent, reag. ISO, reag. Ph. Eur., ≥99.5%

别名:

卤砂

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About This Item

线性分子式:
NH4Cl
CAS号:
12125-02-9
分子量:
53.49
Beilstein:
4371014
EC 号:
235-186-4
MDL编号:
MFCD00011420
UNSPSC代码:
12352300
eCl@ss:
38050207
PubChem化学物质编号:
329753648
NACRES:
NA.21
方案:
≥99.5%
表单:
crystalline powder

等级

ACS reagent
puriss. p.a.

质量水平

100

Agency

USP/NF
reag. ISO
reag. Ph. Eur.

蒸汽密度

1.9 (vs air)

蒸汽压

1 mmHg ( 160.4 °C)

方案

≥99.5%

表单

crystalline powder

杂质

acidity or alkalinity, complies
 bromides and iodides, complies
≤0.005% insoluble matter

pH值（酸碱度）

4.5-5.5 (20 °C, 5%)

mp

340 °C (subl.) (lit.)

痕量阴离子

nitrate (NO3-): ≤5 mg/kg
phosphate (PO43-): ≤2 mg/kg
sulfate (SO42-): ≤20 mg/kg

痕量阳离子

As: ≤0.00005%
Ca: ≤0.0005%
Cu: ≤0.0002%
Fe: ≤0.0002%
K: ≤0.005%
Mg: ≤0.0005%
Na: ≤0.005%
Ni: ≤0.0001%
Pb: ≤0.0001%
Zn: ≤0.0002%
heavy metals: ≤5 mg/kg (by ICP-OES)

适用性

complies for appearance of solution

SMILES字符串

N.Cl

InChI

1S/ClH.H3N/h1H;1H3

InChI key

NLXLAEXVIDQMFP-UHFFFAOYSA-N

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应用

Ammonium chloride can be used as a catalyst:
  • To synthesize 3,4-dihydropyrimidin-2-(1H)-ones via solvent-free Biginelli condensation reaction.
  • For the aldol condensation of carbonyl compounds.
  • In the thia-Michael addition reaction of thiols to different α-enones.
It can also be used as:
  • A promoter in the enantioselective hydrogenation of an unprotected β-enamine amides.
  • A pH-adjuster in the preparation of waterborne glucose silicone resin.

象形图

Exclamation mark
GHS07

警示用语：

Warning

危险声明

H302,H319

危险分类

Acute Tox. 4 Oral - Eye Irrit. 2

储存分类代码

13 - Non Combustible Solids

WGK

WGK 1

闪点(°F)

Not applicable

闪点(°C)

Not applicable

法规信息

新产品

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
STBL4210
STBL1704
STBK7722
STBL0021
STBK5977

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Physical and mechanical properties of poplar wood modified by glucose-urea-melamine resin/sodium silicate compound
Liu Q, et al.
Forests, 12, 127-127 (2021)
Ammonium chloride-catalyzed one-pot synthesis of 3, 4-dihydropyrimidin-2-(1H)-ones under solvent-free conditions
Shaabani A, et al.
Tetrahedron Letters, 44, 857-859 (2003)
Ammonium chloride-catalyzed carbon-sulfur bond formation in water
Chen W, et al.
Catalysis Communications, 9, 1079-1081 (2008)
Identification of ammonium chloride as an effective promoter of the asymmetric hydrogenation of a beta-enamine amide
Clausen A, et al.
Organic Process Research & Development, 10, 723-726 (2006)
The Vibrational Spectra of Molecules and Complex Ions in Crystals III. Ammonium Chloride and Deutero-Ammonium Chloride.
Wagner EL and Hornig DF.
J. Chem. Phys. , 18(3), 296-304 (1950)
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