305197
苯甲醇
anhydrous, 99.8%
别名:
苄醇, 苯甲醇
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关于此项目
线性分子式:
C6H5CH2OH
化学文摘社编号:
分子量:
108.14
NACRES:
NA.21
PubChem Substance ID:
eCl@ss:
39023110
UNSPSC Code:
12352104
EC Number:
202-859-9
MDL number:
Beilstein/REAXYS Number:
878307
Grade:
anhydrous
Assay:
99.8%
Bp:
203-205 °C (lit.)
Vapor pressure:
13.3 mmHg ( 100 °C)
3.75 mmHg ( 77 °C)
3.75 mmHg ( 77 °C)
产品名称
苯甲醇, anhydrous, 99.8%
InChI key
WVDDGKGOMKODPV-UHFFFAOYSA-N
InChI
1S/C7H8O/c8-6-7-4-2-1-3-5-7/h1-5,8H,6H2
SMILES string
OCc1ccccc1
grade
anhydrous
vapor density
3.7 (vs air)
vapor pressure
13.3 mmHg ( 100 °C)
3.75 mmHg ( 77 °C)
assay
99.8%
form
liquid
autoignition temp.
817 °F
expl. lim.
0.34-6.3 %
impurities
<0.003% water
<0.005% water (100 mL pkg)
refractive index
n20/D 1.539 (lit.)
bp
203-205 °C (lit.)
mp
−16-−13 °C (lit.)
solubility
water: soluble 33 g/L at 20 °C
density
1.045 g/mL at 25 °C (lit.)
Quality Level
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Application
苄醇与亚磷酸三乙酯和碘化锌反应生成相应的磷酸盐。还可用于在碳酸氢钠存在下与溴乙酰溴反应制备溴乙酸苄酯。
General description
苄醇是一种单芳香族初级醇，广泛用作溶剂和化妆品配方、医药和香料/香料工业的中间体.它能形成分子内OH....π氢键并以扭式 顺式 构象存在于醇基周围。
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2
存储类别
10 - Combustible liquids
wgk
WGK 1
flash_point_f
213.8 °F - DIN 51758
flash_point_c
101 °C - DIN 51758
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
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David Schilter D and Bielawski CW
Organic Syntheses, 93, 413-413 (2016)
Convenient Synthesis of a-Diazoacetates from a-Bromoacetates and N,N'-Ditosylhydrazine: Preparation of Benzyl Diazoacetate
Ideue E, et al.
Organic Syntheses, 89, 501-501 (2012)
Surface functionalized TiO2 supported Pd catalysts for solvent-free selective oxidation of benzyl alcohol.
Weerachawanasak P, et al.
Catalysis Today, 250, 218-225 (2015)
The most stable conformer of benzyl alcohol.
Miller BJ, et al.
Chemical Physics Letters, 466(1), 21-26 (2008)
Engineering Escherichia coli for renewable benzyl alcohol production.
Pugh S, et al.
Metabolic Engineering Communications, 2, 39-45 (2015)
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