推荐产品
蒸汽密度
2.8 (vs air)
质量水平
蒸汽压
160 mmHg ( 20 °C)
检测方案
≥99.0%
自燃温度
590 °F
包含
100 ppm BHT as inhibitor
expl. lim.
5 %
蒸发残留物
≤0.01%
折射率
n20/D 1.446 (lit.)
n20/D 1.446
bp
83 °C (lit.)
mp
−104 °C (lit.)
密度
0.811 g/mL at 25 °C (lit.)
SMILES字符串
C1CCC=CC1
InChI
1S/C6H10/c1-2-4-6-5-3-1/h1-2H,3-6H2
InChI key
HGCIXCUEYOPUTN-UHFFFAOYSA-N
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应用
在甘油基溶剂中，以双 [3,5-双（三氟甲基）二苯基] 二硒醚为催化剂，通过过氧化氢环氧化反应合成环己烯氧化物。在过氧钨-草酸络合物催化剂存在下也可发生过氧化氢氧化反应生成己二酸。
警示用语：
Danger
危险分类
Acute Tox. 4 Oral - Aquatic Chronic 2 - Asp. Tox. 1 - Flam. Liq. 2
WGK
WGK 2
闪点(°F)
1.4 °F
闪点(°C)
-17 °C
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
Epoxidation of cyclooctene and cyclohexene with hydrogen peroxide catalyzed by bis [3, 5-bis (trifluoromethyl)-diphenyl] diselenide: Recyclable catalyst-containing phases through the use of glycerol-derived solvents
Garcia-Marin H, et al.
J. Mol. Catal. A: Chem., 334(1), 83-88 (2011)
Aerobic oxidative Heck/dehydrogenation reactions of cyclohexenones: efficient access to meta-substituted phenols.
Yusuke Izawa et al.
Angewandte Chemie (International ed. in English), 52(13), 3672-3675 (2013-02-21)
Sylvain Dalençon et al.
The Journal of organic chemistry, 76(19), 8059-8063 (2011-08-26)
The asymmetric synthesis of novel cyclohexene nucleoside analogues 12 and 15 is described. An enantiospecific Diels-Alder reaction between (E,E)-diene 2 and (+)-5-(d-mentyloxy)-2(5H)-furanone 3 provided the cycloadduct isomer 4. Three additional steps yielded amine 8 allowing the constructions of the thymine
Hikaru Yanai et al.
Chemical communications (Cambridge, England), 47(25), 7245-7247 (2011-05-25)
In the absence of any additional catalysts, the reactions of (CF(3)SO)(2)CH(2), aldehydes, and 1,3-dienes gave gem-bis(triflyl)cyclohexenes in excellent yields with high regioselectivity. gem-Bis(triflyl)cyclohexene products can be easily converted to the corresponding aryl trifluoromethyl sulfones.
Oxidative decarboxylation of benzilic acid by a biomimetic iron(II) complex: evidence for an iron(IV)-oxo-hydroxo oxidant from O2.
Sayantan Paria et al.
Angewandte Chemie (International ed. in English), 50(47), 11129-11132 (2011-10-01)
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