等级
anhydrous
质量水平
蒸汽密度
2.1 (vs air)
蒸汽压
32.91 psi ( 55 °C)
9.47 psi ( 20 °C)
检测方案
99%
形式
liquid
自燃温度
842 °F
expl. lim.
23 %
杂质
<0.005% water
蒸发残留物
<0.0005%
折射率
n20/D 1.343 (lit.)
pH值（酸碱度）
4-5 (20 °C, 200 g/L)
bp
32-34 °C (lit.)
mp
−100 °C (lit.)
密度
0.974 g/mL at 20 °C (lit.)
SMILES字符串
[H]C(=O)OC
InChI
1S/C2H4O2/c1-4-2-3/h2H,1H3
InChI key
TZIHFWKZFHZASV-UHFFFAOYSA-N
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应用
甲酸甲酯可用于合成以下构件：
- 4-氯丁酸甲酯经-甲酰化生成 4-氯-2-甲酰丁酸甲酯
- 来自 α-[（甲氧基亚乙基）氨基] 乙酸甲酯的 α-[（甲氧基亚乙基）氨基]-β-羟基丙烯酸钾
- (S)-(-)-1-甲酰基-2-羟甲基吡咯烷经N-甲酰化生成 (S)-(+)-2-羟甲基吡咯烷
警示用语：
Danger
危险分类
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Irrit. 2 - Flam. Liq. 1 - STOT SE 1 - STOT SE 3
靶器官
Respiratory system
WGK
WGK 2
闪点(°F)
-2.2 °F
闪点(°C)
-19 °C
个人防护装备
Eyeshields, Faceshields, Gloves
法规信息
危险化学品
4-Methoxycarbonyl-2-methyl-1,3-oxazole
White JD, et al
Organic Syntheses, 79, 244-244 (2002)
(S)-(-)-1-Amino-2-Methoxymethylpyrrolidine (SAMP) and (R)-(+)-1-Amino-2-Methoxymethylpyrrolidine (RAMP), Versatile Chiral Auxiliaries
Enders D, et al.
Organic Syntheses, 65, 173-173 (1987)
Methyl N-Phenyl Carbamate Synthesis from Aniline and Methyl Formate: Carbon Recycling to Chemical Products.
Yalfani MS, et al.
ChemSusChem, 8(3), 443-447 (2015)
Synthesis of Methyl 1-Formylcyclopropanecarboxylate utilizing Ti-Claisen Condensation
Ashida Y, et al.
Organic Syntheses, 93, 286-286 (2016)
Katherine R Phillips et al.
Journal of the American Chemical Society, 135(2), 574-577 (2012-12-28)
Methyl formate is produced from the photo-oxidation of methanol on preoxidized TiO(2)(110). We demonstrate that two consecutive photo-oxidation steps lead to methyl formate using mass spectrometry and scanning tunneling microscopy. The first step in methanol oxidation is formation of methoxy
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