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Merck
CN

27690

Sigma-Aldrich

2,4,6-三甲基吡啶

puriss. p.a., 99% (GC)

别名:

2,4,6-三甲基氮杂苯, 对称-三甲基吡啶

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About This Item

经验公式(希尔记法):
C8H11N
CAS号:
分子量:
121.18
Beilstein:
107283
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.21

等级

puriss. p.a.

质量水平

方案

99% (GC)

表单

liquid

杂质

≤0.1% water

蒸发残留物

≤0.1%

折射率

n20/D 1.498 (lit.)
n20/D 1.498

沸点

171-172 °C (lit.)

mp

−43 °C (lit.)

密度

0.917 g/mL at 25 °C (lit.)

痕量阳离子

Al: ≤0.5 mg/kg
Ba: ≤0.1 mg/kg
Bi: ≤0.1 mg/kg
Ca: ≤0.5 mg/kg
Cd: ≤0.05 mg/kg
Co: ≤0.02 mg/kg
Cr: ≤0.02 mg/kg
Cu: ≤0.02 mg/kg
Fe: ≤0.1 mg/kg
K: ≤0.5 mg/kg
Li: ≤0.1 mg/kg
Mg: ≤0.1 mg/kg
Mn: ≤0.02 mg/kg
Mo: ≤0.1 mg/kg
Na: ≤0.5 mg/kg
Ni: ≤0.02 mg/kg
Pb: ≤0.1 mg/kg
Sr: ≤0.1 mg/kg
Zn: ≤0.1 mg/kg

储存温度

2-8°C

SMILES字符串

Cc1cc(C)nc(C)c1

InChI

1S/C8H11N/c1-6-4-7(2)9-8(3)5-6/h4-5H,1-3H3

InChI key

BWZVCCNYKMEVEX-UHFFFAOYSA-N

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一般描述

2,4,6-三甲基吡啶是一种杂环芳香族化合物,常用于脱氢卤化反应。由于它的基本性质,在有机反应中也用作反应溶剂或化学添加剂。

应用

2,4,6-三甲基吡啶可用作以下反应的试剂:      
  • 固相肽合成。     
  • 通过与HAuCl4反应合成三氯(2,4,6-三甲基吡啶) Au(III)络合物。

用作电子显微镜的组织固定剂。

象形图

FlameSkull and crossbones

警示用语:

Danger

危险分类

Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

3 - Flammable liquids

WGK

WGK 3

闪点(°F)

131.0 °F - closed cup

闪点(°C)

55 °C - closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

危险化学品

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分析证书(COA)

Lot/Batch Number

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访问文档库

Assessing the acid properties of desilicated ZSM-5 by FTIR using CO and 2, 4, 6-trimethylpyridine (collidine) as molecular probes.
Holm MS, et al.
Applied Catalysis A: General, 356(1), 23-30 (2009)
Halogen complexes. III. The association of 2, 4, 6-trimethylpyridine and trifluoroiodomethane.
Larsen DW and Allred AL.
The Journal of Physical Chemistry, 69(7), 2400-2401 (1965)
J Hasegawa et al.
Journal of pharmaceutical sciences, 73(4), 442-445 (1984-04-01)
The pKa of verapamil was determined by measuring the partition coefficient of verapamil between n-heptane and aqueous buffer solution at various pH values. The magnitude of the effects of ionic strength or temperature on the pKa of verapamil was in
J L Tomsig et al.
Histochemistry, 87(1), 21-25 (1987-01-01)
Rat pineal nerve endings contain a population of small and of large synaptic vesicles that are either electron lucent or have electron-dense cores. It has been reported that their osmiophilia is eliminated when collidine buffer is used in the fixation
Christa A Currie et al.
Journal of chromatography. B, Analytical technologies in the biomedical and life sciences, 824(1-2), 201-205 (2005-08-09)
Microchip capillary electrophoresis (CE), coupled with indirect fluorescence detection was investigated for estimating the pK(a) values of non-fluorescent compounds. The CE method is based on the differences in electrophoretic mobility of the analyte as a function of the pH of

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