等级
anhydrous
质量水平
蒸汽密度
2.6 (vs air)
蒸汽压
70 mmHg ( 20 °C)
检测方案
99.8%
形式
liquid
自燃温度
525 °F
包含
~75 ppm BHT as inhibitor
杂质
<0.003% water
<0.005% water (100 mL pkg)
蒸发残留物
<0.0005%
折射率
n20/D 1.401 (lit.)
bp
75-76 °C/1.013 hPa
mp
−95 °C (lit.)
密度
1.06 g/mL at 25 °C (lit.)
SMILES字符串
C1COCO1
InChI
1S/C3H6O2/c1-2-5-3-4-1/h1-3H2
InChI key
WNXJIVFYUVYPPR-UHFFFAOYSA-N
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一般描述
1,3-二恶烷是一种杂环乙缩醛，常用作制剂和生产工艺中的绿色溶剂。它还可用作有机合成中的反应物。1,3-二恶烷的长期储存会形成有机过氧化物。可通过添加丁基羟基甲苯(BHT)作为稳定剂而抑制这一过程。BHT能去除形成过氧化物所需的自由基。
应用
1,3-二恶烷可用作以下反应的溶剂：
它也可作为反应物用于通过Sc(OTf)3催化的开环聚合反应制备准固态聚1,3-二恶烷电极。
- 从生物质中提取可生物降解的聚(3-羟基丁酸)（PHB）。
- 生产稳定的多壁碳纳米管(MWCNT)分散液用于合成修饰玻璃碳电极。
- 在maghnite-H+ 催化剂存在的情况下通过1;3;5-三恶烷的阳离子共聚反应合成共聚物（聚氧亚甲基）。
它也可作为反应物用于通过Sc(OTf)3催化的开环聚合反应制备准固态聚1,3-二恶烷电极。
警示用语：
Danger
危险声明
危险分类
Eye Irrit. 2 - Flam. Liq. 2 - Repr. 1B
WGK
WGK 1
闪点(°F)
closed cup
闪点(°C)
closed cup
个人防护装备
Eyeshields, Faceshields, Gloves
法规信息
危险化学品
1, 3-Dioxolane: A green solvent for the preparation of carbon nanotube-modified electrodes.
Moscoso R, et al.
Electrochemical Communications, 48, 69-72 (2014)
Binary electrolyte based on tetra (ethylene glycol) dimethyl ether and 1, 3-dioxolane for lithium-sulfur battery.
Chang DR, et al.
Journal of Power Sources, 112(2), 452-460 (2002)
Matthias Schmidt et al.
Bioorganic & medicinal chemistry, 15(6), 2283-2297 (2007-02-06)
Multidrug resistance (MDR) to antitumor agents represents a major obstacle to a successful chemotherapy of cancer. Overexpression of P-glycoprotein (p-gp) seems to be the major factor responsible for MDR. A large number of chemically unrelated compounds are known to interact
Benito Alcaide et al.
The Journal of organic chemistry, 78(18), 8956-8965 (2013-09-07)
The gold-catalyzed preparation of 2-azetidinone-fused oxacycles was accomplished from β-lactam-linked enynes through heterocyclization reaction taking advantage of the acetonide pendant group. While the synthesis of fused tetrahydrofuran-β-lactams from 1,3-enynes could be considered as an unusual metal-catalyzed cyclization of enynols, α-alkoxy
Benjamin L Wegenhart et al.
Inorganic chemistry, 49(11), 4741-4743 (2010-05-06)
Low catalyst loading of a cationic oxorhenium(V) oxazoline complex, [2-(2'-hydroxyphenyl)-2-oxazolinato(-2)]oxorhenium(v), condenses diols and aldehydes to give 1,3-dioxolanes in excellent yields under neat conditions and reasonably mild temperatures. The reaction is applicable to biomass-derived furfural and glycerol. The resulting cyclic acetals
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