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Merck
CN

26049

Supelco

偶氮氯膦 III

for spectrophotometric det. of alkaline earth metals

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别名:
2,7-双(4-氯-2-膦羧苯偶氮)-1,8-二羟基萘-3,6-二磺酸
经验公式(希尔记法):
C22H16Cl2N4O14P2S2
CAS号:
分子量:
757.36
Beilstein:
2934871
EC 号:
MDL编号:
UNSPSC代码:
12000000
PubChem化学物质编号:
NACRES:
NA.21

形式

powder

质量水平

质量

for spectrophotometric det. of alkaline earth metals

技术

UV/Vis spectroscopy: suitable

SMILES字符串

Oc1c(\N=N\c2ccc(Cl)cc2P(O)(O)=O)c(cc3cc(c(\N=N\c4ccc(Cl)cc4P(O)(O)=O)c(O)c13)S(O)(=O)=O)S(O)(=O)=O

InChI

1S/C22H16Cl2N4O14P2S2/c23-10-1-3-12(14(7-10)43(31,32)33)25-27-19-16(45(37,38)39)5-9-6-17(46(40,41)42)20(22(30)18(9)21(19)29)28-26-13-4-2-11(24)8-15(13)44(34,35)36/h1-8,29-30H,(H2,31,32,33)(H2,34,35,36)(H,37,38,39)(H,40,41,42)/b27-25+,28-26+

InChI key

LMBABJNSZGKTBA-NBHCHVEOSA-N

一般描述

Chlorophosphonazo III is a highly sensitive reagent and can be used for the spectrophotometric determination of zirconium, titanium, thorium and scandium. It also finds application as an extractant, along with 1-butanol as solvent, for determination of micromolar concentrations of Nd(III), Th(IV) and U(VI) in brine. Above all that, it has two long wavelength maxima, one at 620 nm and one at 680 nm.

应用

Chlorophosphonazo III was used as a chromogenic agent along with PVC, during the determination of calcium via a disposable optical sensor.

包装

Bottomless glass bottle. Contents are inside inserted fused cone.

其他说明

在分光光度法测定碱土金属中用到的试剂

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Gloves, type N95 (US)

法规信息

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Wei-Wen Liu et al.
Biomedical optics express, 12(2), 1154-1166 (2021-03-09)
This study demonstrates that chlorophosphonazo III (CPZ III) can be used as a contrast agent for photoacoustic calcium imaging. CPZ III can pass across the plasma membrane for labeling intracellular Ca2+ without cytotoxicity. In optical-resolution photoacoustic microscopy (OR-PAM), the photoacoustic
M. Zenki
Analytical Chemistry, 53, 968-968 (1981)
S M Baylor et al.
The Journal of physiology, 331, 179-210 (1982-10-01)
1. Absorbance changes were measured following stimulation of single muscle fibres injected with the metallochromic indicator dye Arsenazo III. Two dye-related signals can be clearly resolved: (1) an early, transient isotropic signal that appears to be due to the formation
Determination of calcium by a single-use optical sensor.
Capitan VLF
Sensors and Actuators B, Chemical, 71 (1), 140-146 (2000)
Rapid changes in intracellular free calcium concentration. Detection by metallochromic indicator dyes in squid giant axon.
Brown JE
Biophysical Journal, 15 (11), 1155-1155 (1975)

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