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Merck
CN

25508

罗谢尔盐 四水合物

99.0-101.0% (calc. on H2O free substance), solid, puriss., meets analytical specification of Ph. Eur., BP, USP, FC, E 337

别名:

L(+)-酒石酸 钾钠盐, 洛瑟尔氏盐, 罗谢尔盐

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关于此项目

线性分子式:
KOCOCH(OH)CH(OH)COONa · 4H2O
化学文摘社编号:
分子量:
282.22
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
206-156-8
MDL number:
Beilstein/REAXYS Number:
6113568
Assay:
99.0-101.0% (calc. on H2O free substance)
Form:
solid
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产品名称

罗谢尔盐 四水合物, puriss., 99.0-101.0% (calc. on H2O free substance), meets analytical specification of Ph. Eur., BP, USP, FC, E 337

InChI key

VZOPRCCTKLAGPN-ZFJVMAEJSA-L

InChI

1S/C4H6O6.K.Na.4H2O/c5-1(3(7)8)2(6)4(9)10;;;;;;/h1-2,5-6H,(H,7,8)(H,9,10);;;4*1H2/q;2*+1;;;;/p-2/t1-,2-;;;;;;/m1....../s1

SMILES string

O.O.O.O.[Na+].[K+].O[C@H]([C@@H](O)C([O-])=O)C([O-])=O

grade

puriss.

assay

99.0-101.0% (calc. on H2O free substance)

form

solid

optical activity

[α]20/D +28.0 to +30.0°

quality

meets analytical specification of Ph. Eur., BP, USP, FC, E 337

impurities

acidity or alkalinity, in accordance
residual solvent, complies
≤0.001% heavy metals (as Pb)
≤0.003% total nitrogen (N)
≤0.004% ammonium (NH4)
≤0.004% free alkali (as NaOH)
≤0.0075% free acid (as C4H6O6)
24-26% water (Karl Fischer)

loss

21-26% loss on drying, 150 °C, 3 h

pH

6.5-8.5 (20 °C, 1%)

anion traces

chloride (Cl-): ≤20 mg/kg
sulfate (SO42-): ≤50 mg/kg

cation traces

As: ≤1 mg/kg
Ba:, in accordance
Ca: ≤50 mg/kg
Cu: ≤10 mg/kg
Fe: ≤10 mg/kg
Hg: ≤1 mg/kg
Pb: ≤2 mg/kg
Zn: ≤10 mg/kg

suitability

passes test for appearance of solution

Quality Level

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Application

Potassium sodium tartrate tetrahydrate has been used in the β-1,3-glucanase activity assay.
Potassium sodium tartrate tetrahydrate may be used as a component to prepare DNS (3,5- dinitrosalicylic acid) reagent and Fehling′s solution B, which are used in the determination of reducing sugar.

General description

Potassium sodium tartrate tetrahydrate (Rochelle salt) exists in the ferroelectric phase in the temperature range of 255 to 297K. In this phase, it crystallizes in the monoclinic system and exhibits space group P21. Saturated aqueous solution of potassium sodium tartrate (Rochelle salt) has been used for the preparation of its tetrahydrate crystals.
Potassium sodium tartrate tetrahydrate is a ferroelectric crystal with a high piezoelectric effect and electromechanical coupling coefficient.

存储类别

13 - Non Combustible Solids

wgk

WGK 1

ppe

Eyeshields, Gloves, type N95 (US)


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