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等级
ACS reagent
质量水平
蒸汽密度
3.5 (vs air)
蒸汽压
10 mmHg ( 36 °C)
4 mmHg ( 20 °C)
方案
≥98.0%
表单
liquid
自燃温度
629 °F
expl. lim.
10.3 %
杂质
MnO4- reducers, passes test
蒸发残留物
≤0.003%
折射率
n20/D 1.390 (lit.)
沸点
138-140 °C (lit.)
mp
−73 °C (lit.)
溶解性
H2O: slightly soluble
密度
1.08 g/mL (lit.)
痕量阴离子
chloride (Cl-): ≤5 ppm
phosphate (PO43-): ≤0.001%
sulfate (SO42-): ≤5 ppm
痕量阳离子
Fe: ≤5 ppm
heavy metals: ≤2 ppm
官能团
anhydride
ester
SMILES字符串
CC(=O)OC(C)=O
InChI
1S/C4H6O3/c1-3(5)7-4(2)6/h1-2H3
InChI key
WFDIJRYMOXRFFG-UHFFFAOYSA-N
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一般描述
醋酸酐是一种有机溶剂溶于水后,其可经过溶剂分解得到乙酸。它被广泛用于各种醇的乙酰化。Wacher法(起始试剂=烯酮)和Knapsack法(起始试剂=乙醛)已报到可用于工业上制备乙酸酐。
应用
醋酸酐已作为反应组分之一,用于制备:
- 2-乙酰氨基-5-氨基苯磺酸
- 3,3′-双(磺酸根基)-4,4′-双(氯乙酰氨基)偶氮苯(BSBCA)
- 10-乙酸基-9-硝基硬脂酸,烯丙酯
- 9-硝基油酸
警示用语:
Danger
危险分类
Acute Tox. 2 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B
储存分类代码
3 - Flammable liquids
WGK
WGK 1
闪点(°F)
120.2 °F - closed cup
闪点(°C)
49 °C - closed cup
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
易制毒化学品(2类)
Acetylation of anisole by acetic anhydride over a HBEA zeolite-Origin of deactivation of the catalyst.
J. Catal., 177(2), 296-305 (1998)
Nature protocols, 2(2), 251-258 (2007-04-05)
This protocol describes a procedure for the synthesis of 3,3'-bis(sulfonato)-4,4'-bis(chloroacetamido)azobenzene (BSBCA), a water-soluble, thiol-reactive, photo-switchable cross-linker. In addition, a protocol is outlined for installing the cross-linker in an intramolecular fashion onto proteins bearing two surface-exposed Cys residues. BSBCA is designed
Free radical biology & medicine, 59, 14-26 (2012-12-04)
Nitrated fatty acids are the product of nitrogen dioxide reaction with unsaturated fatty acids. The discovery of peroxynitrite and peroxidase-induced nitration of biomolecules led to the initial reports of endogenous nitrated fatty acids. These species increase during ischemia/reperfusion, but concentrations
BMC genomics, 9, 352-352 (2008-07-30)
The Prolactin (PRL) hormone gene family shows considerable variation among placental mammals. Whereas there is a single PRL gene in humans that is expressed by the pituitary, there are an additional 22 genes in mice including the placental lactogens (PL)
Dental materials : official publication of the Academy of Dental Materials, 27(8), 748-754 (2011-04-26)
In this study acetyloxypropylene dimethacrylate was synthesized and proposed as an alternative monomer for triethyleneglycol dimethacrylate (TEGDMA) in dental mixtures. The monomer was prepared by the reaction of glycerol dimethacrylate with acetic anhydride. The exchange reaction was carried out in
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