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Merck
CN

242845

Sigma-Aldrich

乙酸酐

ACS reagent, ≥98.0%

别名:

Acetanhydride, Acetic acid anhydride, Acetyl acetate, Acetyl anhydride, Ethanoic anhydride

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About This Item

线性分子式:
(CH3CO)2O
CAS号:
分子量:
102.09
Beilstein:
385737
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.21

等级

ACS reagent

质量水平

蒸汽密度

3.5 (vs air)

蒸汽压

10 mmHg ( 36 °C)
4 mmHg ( 20 °C)

检测方案

≥98.0%

形式

liquid

自燃温度

629 °F

expl. lim.

10.3 %

杂质

MnO4- reducers, passes test

蒸发残留物

≤0.003%

折射率

n20/D 1.390 (lit.)

bp

138-140 °C (lit.)

mp

−73 °C (lit.)

溶解性

H2O: slightly soluble

密度

1.08 g/mL (lit.)

痕量阴离子

chloride (Cl-): ≤5 ppm
phosphate (PO43-): ≤0.001%
sulfate (SO42-): ≤5 ppm

痕量阳离子

Fe: ≤5 ppm
heavy metals: ≤2 ppm

SMILES字符串

CC(=O)OC(C)=O

InChI

1S/C4H6O3/c1-3(5)7-4(2)6/h1-2H3

InChI key

WFDIJRYMOXRFFG-UHFFFAOYSA-N

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一般描述

醋酸酐是一种有机溶剂溶于水后,其可经过溶剂分解得到乙酸。它被广泛用于各种醇的乙酰化。Wacher法(起始试剂=烯酮)和Knapsack法(起始试剂=乙醛)已报到可用于工业上制备乙酸酐。

应用

醋酸酐已作为反应组分之一,用于制备:
  • 2-乙酰氨基-5-氨基苯磺酸
  • 3,3′-双(磺酸根基)-4,4′-双(氯乙酰氨基)偶氮苯(BSBCA)
  • 10-乙酸基-9-硝基硬脂酸,烯丙酯
  • 9-硝基油酸
可用于在间歇式反应器中通过HBEA沸石乙酰化苯甲醚。

警示用语:

Danger

危险分类

Acute Tox. 2 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B

WGK

WGK 1

个人防护装备

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

法规信息

危险化学品
易制毒化学品(2类)

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分析证书(COA)

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