等级
ACS reagent
质量水平
蒸汽密度
3.22 (185 °C, vs air)
蒸汽压
0.7 mmHg ( 25 °C)
检测方案
≥99.5%
形式
liquid
自燃温度
1139 °F
expl. lim.
11 %
杂质
Hydrocarbons, passes test
Nitrobenzene, passes test (lim. ~0.001%)
≤0.01% chlorobenzene
灼烧残渣
≤0.005%
折射率
n20/D 1.586 (lit.)
bp
184 °C (lit.)
mp
−6 °C (lit.)
溶解性
water: soluble
密度
1.022 g/mL at 25 °C (lit.)
SMILES字符串
Nc1ccccc1
InChI
1S/C6H7N/c7-6-4-2-1-3-5-6/h1-5H,7H2
InChI key
PAYRUJLWNCNPSJ-UHFFFAOYSA-N
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应用
苯胺是一种芳族伯胺，可用作合成3-氯-N-苯基吡啶-2-胺、(Z)-甲基3-(苯基氨基)丁-2-烯酸、2-碘-N-苯基苯甲酰胺、2,4-二氯喹啉和 N-(2-丙基)苯胺等有机中间体的反应物。
生化/生理作用
苯胺的急性毒性涉及其在体内活化为4-羟基苯胺和与血红蛋白形成加合物。 在红细胞中，这与铁的释放和高铁血红蛋白的积累以及溶血性贫血和脾脏炎症的发展有关。长期给药时，在脾脏中常可观察到肿瘤形成。
物理属性
材料在储存期间变暗成为红棕色，但纯度不会受到影响。
警示用语：
Danger
危险分类
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 2 - Eye Dam. 1 - Muta. 2 - Skin Sens. 1 - STOT RE 1
靶器官
Blood
WGK
WGK 3
闪点(°F)
closed cup
闪点(°C)
closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
Synthesis of Quinolines by Electrophilic Cyclization of N-(2-Alkynyl)Anilines: 3-Iodo-4-Phenylquinoline
Chen Y, et al
Organic Syntheses, 89, 294-306 (2012)
Synthesis of Tetrasubstituted 1H-Pyrazoles by Coppermediated
Coupling of Enaminones with Nitriles
Coupling of Enaminones with Nitriles
Suri M and Glorius F
Organic Syntheses, 91, 211-220 (2014)
Atsuhiro Tanaka et al.
Chemical communications (Cambridge, England), 49(25), 2551-2553 (2013-02-21)
A functionalized plasmonic Au/TiO2 photocatalyst with an Ag co-catalyst was successfully prepared by the combination of two types of photodeposition methods, and it quantitatively converted nitrobenzene and 2-propanol to aniline and acetone under irradiation of visible light.
Photocatalytic hydrogenation of nitrobenzene to aniline over tungsten oxide-silver nanowires.
Fu L, et al.
Materials Letters, 142, 201-203 (2015)
Viscosities of Binary Mixtures of Benzyl Acetate with Dioxane, Aniline, and m-Cresol.
Katti PK and Chaudhri MM.
Journal of Chemical and Engineering Data, 9(3), 442-443 (1964)
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