234672
2,2′:6′,2′′-三联吡啶
98%, solid
别名:
α,α′,α″-三联吡啶, 2,6-Di(2-pyridyl)pyridine
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关于此项目
经验公式（希尔记法）:
C15H11N3
化学文摘社编号:
分子量:
233.27
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
214-559-5
MDL number:
Beilstein/REAXYS Number:
11199
产品名称
2,2′:6′,2′′-三联吡啶, 98%
InChI key
DRGAZIDRYFYHIJ-UHFFFAOYSA-N
InChI
1S/C15H11N3/c1-3-10-16-12(6-1)14-8-5-9-15(18-14)13-7-2-4-11-17-13/h1-11H
SMILES string
c1ccc(nc1)-c2cccc(n2)-c3ccccn3
assay
98%
form
solid
mp
89-91 °C (lit.)
Quality Level
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Application
由于存在 3 个近共面的氮供体原子，2,2′:6′,2′′′;-三吡啶可作为金属结合域形成金属-超分子结构。
General description
2,2′:6′,2′′;-三联吡啶是一种三齿配体，可从 2-乙酰吡啶开始分两步制备。它与金属中心配位形成络合物。它也可以合成用于不对称催化的手性衍生物。
signalword
Danger
Hazard Classifications
Acute Tox. 1 Oral - Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
2, 2': 6', 2'-Terpyridine.
Potts KT, et al.
Organic Syntheses, 189-189 (1986)
Complexes of the Ruthenium (II)-2, 2': 6', 2''-terpyridine Family. Effect of Electron-Accepting and-Donating Substituents on the Photophysical and Electrochemical Properties.
Maestri M, et al.
Inorganic Chemistry, 34(10), 2759-2767 (1955)
2, 2?: 6?, 2 ?-Terpyridines: From chemical obscurity to common supramolecular motifs
Constable EC
Chemical Society Reviews, 36(2), 246-253 (2007)
Chiral 2, 2 `-bipyridines, 1, 10-phenanthrolines, and 2, 2 `: 6 `, 2 ``-terpyridines: Syntheses and applications in asymmetric homogeneous catalysis
G Chelucci, et al.
Chemical Reviews, 102, 3129-3170 (2002)
An improved, two-step synthesis of 2, 2?: 6?, 2 ?-terpyridine
Jameson DL & Guise LE
Tetrahedron Letters, 32(18), 1999-2002 (1991)
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