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蒸汽密度
3.74 (vs air)
质量水平
蒸汽压
3.42 psi ( 20 °C)
等级
purum
检测方案
≥98.0% (GC)
形式
liquid
自燃温度
842 °F
折射率
n20/D 1.395 (lit.)
n20/D 1.396
bp
93 °C (lit.)
mp
−81 °C (lit.)
密度
1.139 g/mL at 20 °C
1.135 g/mL at 25 °C (lit.)
SMILES字符串
CCOC(Cl)=O
InChI
1S/C3H5ClO2/c1-2-6-3(4)5/h2H2,1H3
InChI key
RIFGWPKJUGCATF-UHFFFAOYSA-N
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应用
- 红酒中白藜芦醇异构体的GC-MS分析： 采用氯甲酸乙酯用于白藜芦醇异构体衍生化，提高GC-MS分析有效性，对于食品化学的质量控制和膳食补充剂开发十分有益(Di Fabio et al., 2020)。
- 果汁中游离芳香羧酸和酚类的测定： 采用氯甲酸乙酯用于GC-MS快速分析，检验消费品中的酚类生物活性物质，对食品安全和药理学具有重要意义(Incocciati et al., 2021)。
- 二芳基酮的合成： 采用氯甲酸乙酯经由镍催化方法合成二芳基酮(Diaryl Ketones)，对于材料科学研究人员开发新的材料和药物具有重要意义(Shi & Hu, 2019)。
警示用语：
Danger
危险分类
Acute Tox. 2 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Met. Corr. 1 - Skin Corr. 1B
WGK
WGK 1
闪点(°F)
60.8 °F
闪点(°C)
16 °C
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
监管及禁止进口产品
Man-Jeong Paik et al.
Journal of chromatography. A, 1214(1-2), 151-156 (2008-11-11)
N-ethoxycarbonylation was combined with (S)-1-phenylethylamidation for enantioseparation of amino acids by gas chromatography (GC) and gas chromatography-mass spectrometry (GC-MS) on achiral capillary columns. The method provided complete enantioseparations of 12 amino acids as diastereomeric N-ethoxycarbonyl/(S)-1-phenylethylamides with exceptional resolutions for proline
Nico C van de Merbel et al.
Bioanalysis, 3(17), 1949-1961 (2011-09-09)
Two methods have been developed and validated for the determination of free and total dopamine in human plasma. They are based on solid-phase extraction of the analyte from the matrix by covalent complexation with phenylboronic acid, followed by derivatization with
Jinmao You et al.
Analytica chimica acta, 658(1), 98-105 (2010-01-20)
An improved reagent named 2-[2-(dibenzocarbazole)-ethoxy] ethyl chloroformate (DBCEC-Cl) for the determination of aliphatic amines by high-performance liquid chromatography (HPLC) with fluorescence detection and post-column online atmospheric chemical ionization-mass spectrometry (APCI-MS) identification has been developed. DBCEC-Cl could easily and quickly label
Tan Guo et al.
Journal of the American Society for Mass Spectrometry, 18(5), 817-825 (2007-03-06)
Beta-methylamino-L-alanine (BMAA) is a neurotoxic amino acid that can be produced by cyanobacteria in aqueous environments. To analyze this compound by gas chromatography/mass spectrometry (GC/MS), BMAA must be derivatized to a nonpolar, volatile compound. This can be accomplished by reacting
Christian Fernandes et al.
Analytica chimica acta, 614(2), 201-207 (2008-04-19)
This article presents a method employing stir bar sorptive extraction (SBSE) with in situ derivatization, in combination with either thermal or liquid desorption on-line coupled to gas chromatography-mass spectrometry for the analysis of fluoxetine in plasma samples. Ethyl chloroformate was
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